Metallomimetic Chemistry of Boron.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.8b00561
Abstract: The study of main-group molecules that behave and react similarly to transition-metal (TM) complexes has attracted significant interest in recent decades. Most notably, the attractive idea of replacing the all-too-often rare and costly metals from… read more here.
Keywords: chemistry boron; chemistry; main group; metallomimetic chemistry ... See more keywords
Metallomimetic Chemistry of a Cationic, Geometrically Constrained Phosphine in the Catalytic Hydrodefluorination and Amination of Ar–F Bonds
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c13318
Abstract: The synthesis, isolation, and reactivity of a cationic, geometrically constrained σ3-P compound in the hexaphenyl-carbodiphosphoranyl-based pincer-type ligand (1+) are reported. 1+ reacts with electron-poor fluoroarenes via an oxidative addition-type reaction of the C–F bond to… read more here.
Keywords: metallomimetic chemistry; chemistry; geometrically constrained; catalytic hydrodefluorination ... See more keywords