Metalloporphyrin Frameworks to Encapsulate Copper Oxides for Boosting Ethylene Production in Neutral Electrolyte
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202315667
Abstract: Electrochemical carbon dioxide reduction (eCO2R) in neutral electrolytes represents a viable solution for alleviating energy and carbon losses associated with carbonate formation, but limited by suboptimal C2+ selectivity and productivity owing to the higher C−C… read more here.
Keywords: spectroscopy; metalloporphyrin frameworks; copper oxides; encapsulate copper ... See more keywords
Plasma–Liquid‐Induced Synthesis of Scandium–Metalloporphyrin Frameworks for Boosted Sensing and Photosensitization
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Materials"
DOI: 10.1002/adma.202412071
Abstract: Inserting metal ions into the porphyrin ring is one of the primary strategies to enhance the properties of porphyrin‐based metal–organic frameworks (MOFs). However, the straightforward, rapid, and energy‐efficient synthesis of porphyrin‐based MOFs with high metallization… read more here.
Keywords: synthesis scandium; metalloporphyrin frameworks; synthesis; scandium metalloporphyrin ... See more keywords
Supercritical CO2 Synthesis of Porous Metalloporphyrin Frameworks: Application in Photodynamic Therapy
Sign Up to like & getrecommendations! Published in 2023 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.2c03018
Abstract: A series of porous metalloporphyrin frameworks prepared from the 5,10,15,20-tetra(4-pyridyl)porphyrin (H2TPyP) linker and four metal complexes, M(hfac)2 M = Cu(II), Zn(II), Co(II), and Ni(II) (hfac: 1,1,1,5,5,5-hexafluoroacetylacetonate), were obtained using supercritical CO2 (scCO2) as a solvent.… read more here.
Keywords: porous metalloporphyrin; metalloporphyrin frameworks; supercritical co2; photodynamic therapy ... See more keywords
Three metalloporphyrin frameworks containing imidazole groups: synthesis, characterization and properties
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry frontiers"
DOI: 10.1039/c6qi00381h
Abstract: In this paper, we designed and synthesized three novel free-base imidazolyl porphyrins via the Macdonald [2 + 2] method, and their reactions with different metal ions afforded three new metalloporphyrin frameworks (MPFs) [Co(tBu-Ph)2(Im-Ph)2Por]·2DMF (1), [Co(F3-Ph)2(Im-Ph)2Por]·1.5DMF… read more here.
Keywords: groups synthesis; containing imidazole; frameworks containing; imidazole groups ... See more keywords