Metalloradical catalysis: A radically different approach for molecular construction
Sign Up to like & getrecommendations! Published in 2021 at "Chem"
DOI: 10.1016/j.chempr.2021.04.004
Abstract: Download : Download high-res image (333KB) Download : Download full-size image Cindy is currently a graduate student in the Department of Chemistry at Boston College. Under the supervision of Professor Peter Zhang, Cindy’s PhD research… read more here.
Keywords: radically different; download; metalloradical catalysis; catalysis radically ... See more keywords
Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b05778
Abstract: Cobalt(II)-based metalloradical catalysis has been successfully applied to radical bicyclization of allyl azidoformates to construct aziridine/oxazolidinone-fused bicyclic structures. The Co(II) complex of D2-symmetric chiral amidoporphyrin 3,5-DitBu-QingPhyrin has been identified as an effective metalloradical catalyst for… read more here.
Keywords: metalloradical catalysis; cobalt based; bicyclization allyl; based metalloradical ... See more keywords