Metallosupramolecular cages: from design principles and characterisation techniques to applications.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Society reviews"
DOI: 10.1039/d1cs01143j
Abstract: Although metallosupramolecular cages are self-assembled from seemingly simple building blocks, metal ions and organic ligands, architectures of increasingly large size and complexity are accessible and exploited in applications from catalysis to the stabilisation of reactive… read more here.
Keywords: design principles; principles characterisation; cages design; metallosupramolecular cages ... See more keywords
Hierarchical packing of racemic metallosupramolecular cages with Ni(II)-based triple-stranded helicate building blocks
Sign Up to like & getrecommendations! Published in 2023 at "IUCrJ"
DOI: 10.1107/s2052252523002385
Abstract: Racemic metallosupramolecular cages were fabricated from homochiral Ni(II)-based triple-stranded helicate building blocks. In hierarchical crystal packing, methyl groups of a cage can be accommodated in cone-shaped metal cluster metallocavitands of adjacent cages in the form… read more here.
Keywords: based triple; stranded helicate; racemic metallosupramolecular; helicate building ... See more keywords