Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand
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DOI: 10.1021/acscatal.0c02779
Abstract: Syntheses and catalytic application of rhodium complexes having a pincer-type group 13 metallylene ligand are reported. The PGaIP–Rh complex exhibited high chemoselectivity for hydrosilylation of n... read more here.
Keywords: type group; metallylene ligand; rhodium; group metallylene ... See more keywords