Synthesis, crystal structure and magnetic properties of a cyanide-bridged one-dimensional FeIIICoII metamagnet
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DOI: 10.1016/j.ica.2018.05.030
Abstract: Abstract A new cyanide-bridged FeIIICoII bimetallic complex {[Fe(Tp)(CN)3Co(LN3O2)]ClO4·2H2O}n (Tp− = hydrotris(pyrazolyl)borate, LN3O2 = 2,13-dimethyl-6,9-dioxa-3,12,18-triaza-bicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentene) (1) has been synthesized based on the building blocks of [CoII(LN3O2)(H2O)2](ClO4)2 and Bu4N[FeIII(Tp)(CN)3]. X-ray single crystal diffraction analysis shows that complex 1 has a cyanide-bridged… read more here.
Keywords: cyanide bridged; one dimensional; structure magnetic; metamagnet ... See more keywords