Pd-Modified ZnO-Au Enabling Alkoxy Intermediates Formation and Dehydrogenation for Photocatalytic Conversion of Methane to Ethylene.
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DOI: 10.1021/jacs.0c10369
Abstract: Photocatalysis provides an intriguing approach for the conversion of methane to multicarbon (C2+) compounds under mild conditions; however, with methyl radicals as the sole reaction intermediate, the current C2+ products are dominated by ethane, with… read more here.
Keywords: dehydrogenation; methane ethylene; conversion; methane ... See more keywords
Conversion of methane to ethylene using an Ir complex and phosphorus ylide as a methylene transfer reagent.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc08761j
Abstract: Cp*(Me3P)Ir(CH3)(OTf), a complex known to reversibly activate CH4 and other hydrocarbons under mild conditions, reacts with the phosphorus ylide H2CPPh3 in THF to afford two major species [Cp*(Me3P)(Ph3P)Ir(CH2CH3)][OTf] and [Cp*(Me3P)Ir(H)(η2-CH2CH2)][OTf]. Insertion of the ylide methylene… read more here.
Keywords: methane ethylene; phosphorus ylide; ylide methylene; conversion methane ... See more keywords