Advanced X‐ray Absorption Spectroscopy Analysis to Determine Structure‐Activity Relationships for Cu‐Zeolites in the Direct Conversion of Methane to Methanol
Sign Up to like & getrecommendations! Published in 2020 at "ChemCatChem"
DOI: 10.1002/cctc.201902371
Abstract: An industrial process for direct conversion of methane to methanol (DMTM) would revolutionize methane as feedstock for the chemical industry and it would be a cherished contribution to climate change mitigation. At the present stage,… read more here.
Keywords: methane methanol; conversion; direct conversion; spectroscopy ... See more keywords
Comparison of mechanisms for the direct, gas phase, partial oxidation of methane to methanol
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.116718
Abstract: Abstract Numerous mechanisms have been proposed for the direct, homogeneous, partial oxidation of methane to methanol system. No thorough comparison of them to experimental data, and to each other, has been reported. In this work… read more here.
Keywords: partial oxidation; methane methanol; oxidation methane; methane ... See more keywords
Conversion of methane to methanol on C-doped boron nitride: A DFT study
Sign Up to like & getrecommendations! Published in 2021 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2021.113291
Abstract: Abstract Computational modeling of the methane-to-methanol catalytic conversion reaction on the carbon-boron nitride nanosheet (C-BNN) was reported with the density functional theory. The charge density on C-BNN was displayed with the electron density difference map… read more here.
Keywords: conversion; reaction; boron nitride; methane methanol ... See more keywords
Stimulation of cell growth by addition of tungsten in batch culture of a methanotrophic bacterium, Methylomicrobium alcaliphilum 20Z on methane and methanol.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of biotechnology"
DOI: 10.1016/j.jbiotec.2019.12.021
Abstract: It is carried out for researches to convert methane, the second most potent greenhouse gas, to high-value chemicals and fuels by using methanotrophs. In this study, we observed that cell growth of Methylomicrobium alcaliphilum 20Z… read more here.
Keywords: methane methanol; methylomicrobium alcaliphilum; addition tungsten; cell growth ... See more keywords
Radical-initiated oxidative conversion of methane to methanol over metallic iron and copper catalysts
Sign Up to like & getrecommendations! Published in 2018 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2017.12.001
Abstract: Abstract Oxidative conversion of methane gas into value-added chemicals such as methanol is of great interest due to high economic feasibility of liquid fuel molecules for storage and transportation purpose. Activation and conversion of methane… read more here.
Keywords: methane methanol; oxidative conversion; conversion; methane ... See more keywords
Time-Dependent Density Functional Theory Study of Copper(II) Oxo Active Sites for Methane-to-Methanol Conversion in Zeolites.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03279
Abstract: Copper-exchanged zeolites are useful materials for step-wise methane-to-methanol conversion (MMC). However, methanol yields on copper-exchanged zeolites are often modest, spurring interest in the development of active-site species that are activated at moderate temperatures, afford greater… read more here.
Keywords: active sites; methane methanol; methanol conversion; theory ... See more keywords
Exploring the Tunability of Trimetallic MOF Nodes for Partial Oxidation of Methane to Methanol.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c06241
Abstract: Density functional theory is used to study the tunability of trigonal prismatic SBUs found in metal-organic frameworks (MOFs) such as MIL-100, MIL-101, and PCN-250/MIL-127 of chemical composition M3+2M2+(µ3-O)(RCOO)6 for the partial oxidation of methane to… read more here.
Keywords: partial oxidation; tunability; methane methanol; oxidation methane ... See more keywords
Electrochemical Reoxidation Enables Continuous Methane-to-Methanol Catalysis with Aqueous Pt Salts
Sign Up to like & getrecommendations! Published in 2019 at "ACS Central Science"
DOI: 10.1021/acscentsci.9b00273
Abstract: The direct conversion of methane to methanol would enable better utilization of abundant natural gas resources. In the presence of stoichiometric PtIV oxidants, PtII ions are capable of catalyzing this reaction in aqueous solutions at… read more here.
Keywords: ptiv; methane methanol; oxidation; methanol ... See more keywords
cis-[6-(Pyridin-2-yl)-1,3,5-triazine-2,4-diamine](dichloride) Palladium(II)-Based Electrolyte Membrane Reactors for Partial Oxidation Methane to Methanol
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c01463
Abstract: Methane is an abundant resource and the main constituent of natural gas. It can be converted into higher value-added products and as a subproduct of electricity co-generation. The application of polymer electrolyte reactors for the… read more here.
Keywords: reactors partial; methane methanol; palladium; methane ... See more keywords
Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts
Sign Up to like & getrecommendations! Published in 2017 at "Nature"
DOI: 10.1038/nature24640
Abstract: An efficient and direct method of catalytic conversion of methane to liquid methanol and other oxygenates would be of considerable practical value. However, it remains an unsolved problem in catalysis, as typically it involves expensive… read more here.
Keywords: methane; acetic acid; methane methanol; methanol acetic ... See more keywords
Biological conversion of methane to methanol through genetic reassembly of native catalytic domains
Sign Up to like & getrecommendations! Published in 2019 at "Nature Catalysis"
DOI: 10.1038/s41929-019-0255-1
Abstract: Methane monooxygenase (MMO), which exists in particulate (pMMO) or soluble forms (sMMO) in methanotrophic bacteria, is an industrially promising enzyme that catalyses oxidation of low-reactive methane and other carbon feedstocks into methanol and their corresponding… read more here.
Keywords: methane methanol; methanol; methane; mmo ... See more keywords