A DNA-Threaded ZIF-8 Membrane with High Proton Conductivity and Low Methanol Permeability.
Sign Up to like & getrecommendations! Published in 2018 at "Advanced materials"
DOI: 10.1002/adma.201705155
Abstract: Natural biomolecules have potential as proton-conducting materials, in which the hydrogen-bond networks can facilitate proton transportation. Herein, a biomolecule/metal-organic framework (MOF) approach to develop hybrid proton-conductive membranes is reported. Single-strand DNA molecules are introduced into… read more here.
Keywords: zif membrane; dna; methanol; proton ... See more keywords
Mixed‐Dimensional Pt–Ni Alloy Polyhedral Nanochains as Bifunctional Electrocatalysts for Direct Methanol Fuel Cells
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202206508
Abstract: Pt nanocatalysts play a critical role in direct methanol fuel cells (DMFCs) due to their appropriate adsorption/desorption energy, yet suffer from an unbalanced relationship between size‐dependent activity and stability. Herein, mixed‐dimensional Pt–Ni alloy polyhedral nanochains… read more here.
Keywords: methanol; mixed dimensional; fuel cells; dimensional alloy ... See more keywords
A Single Chamber Direct Methanol Fuel Cell
Sign Up to like & getrecommendations! Published in 2017 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.201700321
Abstract: The complexities associated with H2 storage project liquid fed direct alcohol fuel cells promising alternative to H2-O2 fuel cells. However on the benchmark Pt-based electrocatalytic interface, the multielectron alcohol oxidation kinetics proceed through a parallel… read more here.
Keywords: single chamber; fuel cell; methanol; chamber direct ... See more keywords
Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature
Sign Up to like & getrecommendations! Published in 2020 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202000241
Abstract: A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source… read more here.
Keywords: temperature; hydrogen; methanol; room temperature ... See more keywords
DFT Study of Nickel‐Catalyzed Low‐Temperature Methanol Synthesis
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700213
Abstract: Low‐temperature methanol synthesis (CO+2 H2→CH3OH) catalyzed by a homogeneous nickel/alkali metal alkoxide system has been studied theoretically. Two broad mechanistic possibilities, the direct hydrogenation of CO by nickel formyl species and indirect hydrogenation via methyl formate… read more here.
Keywords: low temperature; methanol; methyl formate; methanol synthesis ... See more keywords
Copper-catalysed formylation of amines using methanol as the C1 source.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.201903266
Abstract: Cu/TEMPO as catalytic system is known for the selective transformation of alcohol to aldehyde as well as the simultaneous coupling of alcohol and amines to imines under oxidative conditions. Herein we demonstrate for the first… read more here.
Keywords: formylation; formylation amines; catalysed formylation; methanol ... See more keywords
CO2 hydrogenation to methanol with Ga- and Zn-doped mesoporous Cu/SiO2 catalysts prepared by the aerosol-assisted sol-gel process.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202001951
Abstract: The preparation of copper-based heterogeneous catalysts dedicated to the hydrogenation of CO 2 to methanol typically relies on multi-step procedures carried out in batch. These steps are precisely tailored to introduce the active phase (Cu)… read more here.
Keywords: hydrogenation methanol; methanol; aerosol assisted; process ... See more keywords
Hydrogenation of Carbon Dioxide to Methanol over Non-Cu - based Heterogeneous Catalysts.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202002054
Abstract: The increasing atmospheric CO 2 level makes CO 2 reduction an urgent challenge facing the world. Catalytic transformation of CO 2 into chemicals and fuels utilizing renewable energy is one of the promising approaches toward… read more here.
Keywords: heterogeneous catalysts; hydrogenation; methanol; based heterogeneous ... See more keywords
CO2 reduction to methanol in the liquid phase: A review.
Sign Up to like & getrecommendations! Published in 2020 at "ChemSusChem"
DOI: 10.1002/cssc.202002087
Abstract: Excessive carbon dioxide (CO 2 ) emission has attracted extensive attention globally since an enhanced greenhouse effect (global warming) due to a high CO 2 concentration in the atmosphere could lead to severe climate change.… read more here.
Keywords: phase; co2 reduction; liquid phase; methanol ... See more keywords
The pH and Potential Dependence of Pb-Catalyzed Electrochemical CO2 Reduction to Methyl Formate in a Dual Methanol/Water Electrolyte.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202102289
Abstract: The conversion of waste CO 2 to value-added chemicals through electrochemical reduction is a promising technology for mitigating climate change while simultaneously providing economic opportunities. The use of non-aqueous solvents like methanol allows for higher… read more here.
Keywords: methanol; potential dependence; water; methyl formate ... See more keywords
REVIEW Recent Advances in the Carbon Dioxide Adsorption, Activation and Hydrogenation to Methanol using Transition Metal Carbides.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202201183
Abstract: The inevitable emission of carbon dioxide (CO 2 ) due to the burning of a substantial amount of fossil fuels has led to serious energy and environmental challenges. Metal-based catalytic CO 2 transformations into commodity… read more here.
Keywords: methanol; adsorption; carbon; hydrogenation ... See more keywords