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Published in 2017 at "Reaction Kinetics, Mechanisms and Catalysis"
DOI: 10.1007/s11144-017-1214-y
Abstract: The kinetics of methanol dehydrogenation over carbon-supported copper catalyst was studied. The catalyst was prepared by the incipient wetness impregnation of carbonaceous graphite-like material Sibunit with aqueous solution of copper nitrate. The resulting Cu/C samples…
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Keywords:
supported copper;
carbon supported;
methanol dehydrogenation;
dehydrogenation ... See more keywords
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Published in 2017 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2017.02.220
Abstract: Abstract Carbon-supported copper catalyst was prepared by incipient wetness impregnation of Sibunit with an aqueous solution of copper nitrate. Copper loading was 5 wt.%. Temperature of reductive pretreatment was varied within a range of 200–400 °C. The…
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Keywords:
supported copper;
copper;
copper catalyst;
carbon supported ... See more keywords
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Published in 2020 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2020.145434
Abstract: Abstract Density functional theory (DFT) was employed to investigate the mechanism of CH3OH dehydrogenation on the PdAu(1 0 0) surface. The adsorption of intermediates involved in the methanol dehydrogenation process was identified and all the elementary reactions…
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Keywords:
dehydrogenation pdau;
surface;
methanol dehydrogenation;
pdau surface ... See more keywords
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Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.08.027
Abstract: Abstract Dehydrogenation is the first reaction of the aqueous phase reforming (APR) mechanism of polyols, and its rate is likely affected by the environment at the active site. This study focuses on reactions of methanol…
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Keywords:
methanol dehydrogenation;
dehydrogenation;
active sites;
effects adsorbed ... See more keywords
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Published in 2022 at "Nanoscale"
DOI: 10.1039/d1nr07947f
Abstract: Methanol dehydrogenation on Pt nanoparticles was studied as a model reaction with the focus on size and structure effects employing the density functional theory approach. The effect of cluster morphology is manifested by the higher…
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Keywords:
size;
structure effects;
size structure;
methanol dehydrogenation ... See more keywords