Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes
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DOI: 10.1021/acs.chemrev.6b00816
Abstract: The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design… read more here.
Keywords: hydrogenation; methanol; formic acid; development ... See more keywords
Effect of surface acidity on the catalytic activity and deactivation of supported sulfonic acids during dehydration of methanol to DME
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DOI: 10.1039/d0nj00229a
Abstract: The influence of a catalyst's surface acidity on the catalytic activity and deactivation in the dehydration of methanol to DME was investigated. Different materials including propylsulfonic acid functionalized silica with different Bronsted acidities, silica–alumina, and… read more here.
Keywords: methanol; acidity; activity; methanol dme ... See more keywords
Selective oxidation conversion of methanol/dimethyl ether.
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DOI: 10.1039/d1cc07276e
Abstract: As important platform compounds, methanol and dimethyl ether (DME) are vital bridges between the coal chemical, petrochemical and fine chemical industries. At present, the synthesis of methanol/DME has been industrialized, and the production capacity is… read more here.
Keywords: methanol; oxidation; dimethyl ether; methanol dimethyl ... See more keywords