Base-controlled divergent synthesis of cyclopropyl aryl methanones from homopropargylic alcohols with DMTST
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DOI: 10.1039/d5cc05964j
Abstract: A method for synthesizing cyclopropyl aryl methanones from homopropargylic alcohols using dimethyl(methylthio)sulfonium trifluoromethanesulfonate has been developed. The reaction selectivity, governing the formation of cyclopropane or methylthio-cyclopropane architectures, is controlled by the choice of base. This… read more here.
Keywords: cyclopropyl aryl; methanones homopropargylic; base controlled; aryl methanones ... See more keywords