Mechanistic insights into the γ-elimination reaction of l-methionine catalyzed by methionine γ-lyase (MGL)
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DOI: 10.1007/s00214-017-2140-9
Abstract: The γ-elimination mechanism of l-methionine catalyzed by methionine γ-lyase was studied by employing the combined quantum mechanics and molecular (QM/MM) calculations. Based on the two crystal structures of methionine γ-lyase from Clostridium sporogenes and Citrobacter… read more here.
Keywords: methionine catalyzed; methionine lyase; catalyzed methionine; aldimine intermediate ... See more keywords
Ac-L-Methionine-Catalyzed, Nitrite-Triggered Cycloaddition Reaction Between Bromide and Alkyne/Alkene: A step-economical reaction for modular synthesis
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DOI: 10.1039/d3qo00549f
Abstract: The development of modular, chemically diverse and regioselective reactions for expanding the cycloaddition reaction toolbox hinges heavily on a strict functional 1,3-dipole and dipolarophile pairing exploration. In this study, we... read more here.
Keywords: methionine catalyzed; reaction; catalyzed nitrite; cycloaddition reaction ... See more keywords