Rhodafuran from a methoxy(alkenyl)carbene by the rhoda-1,3,5-hexatriene route.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01889h
Abstract: A methoxy(alkenyl)carbenerhodium complex [RhCp*Cl{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]CPh2}(PMe3)]PF6 (2) has been synthesized and used as the starting material for the study of the effect of the metal center (Rh vs. Ir)… read more here.
Keywords: bond; carbene; methoxy alkenyl; rhoda hexatriene ... See more keywords
Iridaaromatics via Methoxy(alkenyl)carbeneiridium Complexes
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DOI: 10.3390/molecules26154655
Abstract: This review describes the development of a versatile methodology to synthesize polycyclic metallaaromatic hydrocarbons based on iridium, as well as the studies that helped us to determine and understand what is required in order to… read more here.
Keywords: via methoxy; methodology; alkenyl carbeneiridium; methoxy alkenyl ... See more keywords