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Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.04.036
Abstract: Abstract A DMAP (4-dimethylaminopyridine) catalyzed cyclization of methyl 2-alkynylbenzimidates has been developed, which affords 3-methoxy-1-methyleneisoindoles with excellent Z-stereoselectivity under mild and transition-metal-free conditions. The (Z)-3-methoxy-1-methyleneisoindole products can be converted to corresponding 3-amino-1-methyleneisoindoles, 3-methoxy-isoindoles, 3-methyleneisoindolinones and…
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Keywords:
catalyzed cyclization;
methoxy methyleneisoindoles;
dmap;
methyl alkynylbenzimidates ... See more keywords