Development of a kinetic model of ethylene methoxycarbonylation with homogeneous Pd catalyst using a capillary microreactor
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2017.04.059
Abstract: The kinetics of gas-liquid methoxycarbonylation of ethylene using 0.0013 mol/L Pd(dtbpx)(dba) homogeneous catalyst at 100 °C and 10 bar were studied in a continuous flow Hastelloy capillary microreactor of 1 mm internal diameter. Characterisation of… read more here.
Keywords: capillary microreactor; methoxycarbonylation; model; homogeneous catalyst ... See more keywords
Mechanistic Insight into Palladium/Brønsted Acid Catalyzed Methoxycarbonylation and Hydromethoxylation of Internal Alkene: A Computational Study.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04291
Abstract: Density functional theory (DFT) calculations were performed to study the palladium/Brønsted acid-catalyzed methoxycarbonylation and hydromethoxylation reactions of internal alkene. The calculated results show that the pyridyl group (N atom) in bidentate phosphine ligand with built-in… read more here.
Keywords: hydromethoxylation; palladium nsted; methoxycarbonylation; nsted acid ... See more keywords