Computational Determination of pKa(C–H) in 3d Transition Metal-Methyl Complexes
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00220
Abstract: A DFT study of 76 complexes comprised of 3d transition metals, Ti through Ni, bonded to at least one methyl group was undertaken to compute the Bronsted acidity of methyl C–H bonds. Example complexes were… read more here.
Keywords: methyl; transition metal; metal; methyl complexes ... See more keywords
Formation of an α-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido–Methyl Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00043
Abstract: To probe the reactivity of two potential sites at tetravalent thorium and uranium metal centers, we examined the monophosphido methyl complexes, (C5Me5)2An(CH3)[P(SiMe3)(Mes)], An = Th, U; Mes = 2,... read more here.
Keywords: isocyanide coupling; formation diimine; diimine isocyanide; thorium uranium ... See more keywords