Exploring the Selective Demethylation of Aryl Methyl Ethers with a Pseudomonas Rieske Monooxygenase
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DOI: 10.1002/cbic.201800594
Abstract: Biocatalytic dealkylation of aryl methyl ethers is an attractive reaction for valorization of lignin components, as well as for deprotection of hydroxy functionalities in synthetic chemistry. We explored the demethylation of various aryl methyl ethers… read more here.
Keywords: rieske monooxygenase; aryl methyl; methyl ethers; demethylation ... See more keywords
Determination of Methyl Group Positions in Long-Chain Aliphatic Methyl Ethers and Alcohols by Gas Chromatography/Orbitrap Mass Spectrometry
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DOI: 10.1021/acs.analchem.5c03083
Abstract: Methylated long-chain aliphatic compounds such as terminal methyl ethers are a common compound type found on the epicuticular layer of arthropods, e.g., spiders. Because complex mixtures are encountered in small amounts when analyzing these mixtures,… read more here.
Keywords: chain aliphatic; methyl; group; methyl ethers ... See more keywords
Synthesis of C-prenylated analogues of stilbenoid methyl ethers and their cyclic dihydrobenzopyranyl derivatives as potential anti-inflammatory agents
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DOI: 10.1039/d2ra00441k
Abstract: An efficient and versatile synthesis of the naturally occurring C-prenylated stilbenoid methyl ethers and their synthetic analogues is presented. The synthesis represents a six step convergent process including an optimised C-prenylation method. Furthermore, during the… read more here.
Keywords: stilbenoid methyl; methyl ethers; synthesis; synthesis prenylated ... See more keywords
Nickel-Catalyzed Amination of α-Aryl Methyl Ethers
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DOI: 10.1055/s-0039-1690718
Abstract: α-Aryl amines are prevalent in pharmaceutically active compounds and natural products. Herein, we describe a Ni-catalyzed protocol for their synthesis from readily available α-aryl ethers. While α-aryl ethers have been used as electrophiles in Ni-catalyzed… read more here.
Keywords: aryl methyl; methyl ethers; catalyzed amination; amination aryl ... See more keywords