DFT Study of Nickel‐Catalyzed Low‐Temperature Methanol Synthesis
Sign Up to like & getrecommendations! Published in 2017 at "ChemCatChem"
DOI: 10.1002/cctc.201700213
Abstract: Low‐temperature methanol synthesis (CO+2 H2→CH3OH) catalyzed by a homogeneous nickel/alkali metal alkoxide system has been studied theoretically. Two broad mechanistic possibilities, the direct hydrogenation of CO by nickel formyl species and indirect hydrogenation via methyl formate… read more here.
Keywords: low temperature; methanol; methyl formate; methanol synthesis ... See more keywords
Continuous Hydrogenation of Carbon Dioxide to Formic Acid and Methyl Formate by a Molecular Iridium Complex Stably Heterogenized on a Covalent Triazine Framework
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DOI: 10.1002/cctc.201901179
Abstract: Continuous synthesis of formic acid and methyl formate via CO2 hydrogenation is demonstrated using a molecular iridium complex stably immobilized on a solid covalent triazine framework (CTF) under high‐pressure conditions. Compared to formic acid synthesis,… read more here.
Keywords: methyl formate; acid methyl; formic acid;
The pH and Potential Dependence of Pb-Catalyzed Electrochemical CO2 Reduction to Methyl Formate in a Dual Methanol/Water Electrolyte.
Sign Up to like & getrecommendations! Published in 2022 at "ChemSusChem"
DOI: 10.1002/cssc.202102289
Abstract: The conversion of waste CO 2 to value-added chemicals through electrochemical reduction is a promising technology for mitigating climate change while simultaneously providing economic opportunities. The use of non-aqueous solvents like methanol allows for higher… read more here.
Keywords: methanol; potential dependence; water; methyl formate ... See more keywords
Biodiesel production by interesterification of rapeseed oil with methyl formate in presence of potassium alkoxides
Sign Up to like & getrecommendations! Published in 2020 at "Biomass Conversion and Biorefinery"
DOI: 10.1007/s13399-020-00874-z
Abstract: An alternative method for the biodiesel or fatty acid alkyl ester (FAAE) synthesis has been proposed—rapeseed oil interesterification with methyl formate. Reaction with methyl formate proceeds at a relatively low temperature (28 °C) instead of 55–65 °C… read more here.
Keywords: rapeseed oil; methyl; potassium alkoxides; interesterification ... See more keywords
Quantitative Conversion of Methanol to Methyl Formate on Graphene-Confined Nano-Oxides
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DOI: 10.1016/j.isci.2020.101157
Abstract: Summary We demonstrate the nearly quantitative conversion of methanol to methyl formate (MF) with a reliable durability on the reduced-graphene-oxide-confined VTiOx nanoparticles (rGO@VTiO). The rGO@VTiO exhibits superior low-temperature reactivity than the rGO-free VTiO, and the… read more here.
Keywords: methanol methyl; methanol; methyl formate; conversion methanol ... See more keywords
Reaction Process of Resin-Catalyzed Methyl Formate Hydrolysis in Biphasic Continuous Flow
Sign Up to like & getrecommendations! Published in 2017 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.6b04820
Abstract: In the frame of process development for the generation of chemical energy carriers, we studied the synthesis of methanol and formic acid from methyl formate hydrolysis in a continuous-flow millireactor. The aim was to establish… read more here.
Keywords: methyl formate; process; reaction; continuous flow ... See more keywords
CuO Nanoparticle-Decorated TiO2-Nanotube Heterojunctions for Direct Synthesis of Methyl Formate via Photo-Oxidation of Methanol
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c01169
Abstract: Methyl formate is widely employed as one of the important organic intermediates in C1 chemistry and as an environmentally benign chemical in the emerging area of “green chemistry”. We here study the catalytic effectiveness of… read more here.
Keywords: methyl formate; methyl; cuo tio2; tio2 nanotube ... See more keywords
Studying the kinetics of rapeseed oil reactions with methanol, methyl formate, and methyl acetate under mild conditions for biodiesel production
Sign Up to like & getrecommendations! Published in 2020 at "Biofuels"
DOI: 10.1080/17597269.2020.1827929
Abstract: Abstract The rate constants of the transesterification reactions of rapeseed oil with methanol, methyl formate, and methyl acetate at room temperature in the presence of homogeneous potassium tert-butoxide in tetrahydrofuran were investigated and mutually compared… read more here.
Keywords: methyl acetate; rapeseed oil; methyl formate; oil ... See more keywords
Calculations on the non-classical β-hydride elimination observed in trans-(H)(OMe)-Ir(Ph)(PMe3)3: possible production and reaction of methyl formate
Sign Up to like & getrecommendations! Published in 2020 at "Canadian Journal of Chemistry"
DOI: 10.1139/cjc-2020-0313
Abstract: The octahedral trans hydrido-alkoxide complex trans-(H)(OMe)-Ir(Ph)(PMe3)3 (2-OCH3) was prepared by Milstein and coworkers by addition of methanol to Ir(Ph)(PMe3)3 (1). 2-OCH3 was discovered to undergo a methanol catalyzed outer-sphere carbonyl de-insertion in which a vacant… read more here.
Keywords: methyl formate; trans ome; reaction; och3 ... See more keywords
Predicting dipole orientations in spontelectric methyl formate
Sign Up to like & getrecommendations! Published in 2021 at "European Physical Journal D"
DOI: 10.1140/epjd/s10053-021-00098-4
Abstract: Capturing intermolecular interactions accurately is essential for describing, e.g., morphology of molecular matter on the nanoscale. When it reveals characteristics which are not directly accessible through experiments or ab initio theories, a model here becomes… read more here.
Keywords: predicting dipole; methyl formate; spontelectric methyl; orientations spontelectric ... See more keywords