Exceptionally high molecular weight linear polyethylene by using N,N,N′‐ Co catalysts appended with a N′ ‐2,6‐bis{di(4‐fluorophenyl)methyl}‐4‐nitrophenyl group
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DOI: 10.1002/aoc.5157
Abstract: The bis(arylimino)pyridines, 2-[CMeN{2,6-{(4-FC6H4)2CH}2-4-NO2}]-6-(CMeNAr)C5H3N (Ar = 2,6-Me2C6H3 L1, 2,6-Et2C6H3 L2, 2,6-i-Pr2C6H3 L3, 2,4,6-Me3C6H2 L4, 2,6-Et2-4-MeC6H2 L5), each containing one N'-2,6-bis{di(4-fluorophenyl)methyl}-4-nitrophenyl group, have been synthesized by two successive condensation reactions from 2,6-diacetylpyridine. Their subsequent treatment with anhydrous… read more here.
Keywords: methyl nitrophenyl; fluorophenyl methyl; bis; bis fluorophenyl ... See more keywords
Synthesis, characterization, thermal and DFT studies of S-methyl-β-N-(3-(2-nitrophenyl)allylidene)dithiocarbazate as anti-bacterial agent
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DOI: 10.1016/j.molstruc.2018.06.061
Abstract: Abstract S-Methyl-β-N-(3-(2-nitrophenyl)allylidene)dithiocarbazate (HL), Schiff base of S-methyl dithiocarbazate, was synthesized by 1:1 condensation between S-methyl dithiocarbazate and trans-o-nitro cinnamaldehyde. It's in-vitro cytotoxicity is assayed against two habitually infection causing bacteria strains including gram-positive Staphylococcus aureus… read more here.
Keywords: energy; allylidene dithiocarbazate; dithiocarbazate; methyl nitrophenyl ... See more keywords
(1R,2S,5R)-5-Methyl-2-[2-(4-nitrophenyl)propan-2-yl]cyclohexyl 2-(4-methoxyphenyl)-2,5-dihydro-1H-pyrrole-1-carboxylate: crystal structure and Hirshfeld analysis
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DOI: 10.1107/s2056989018003092
Abstract: The molecule in the title compound approximates a U-shape with the nitrobenzene and ester substituents lying to the same side of the molecule. In the crystal, linear supramolecular chains are sustained by methylene-C—H⋯O(carbonyl) interactions. read more here.
Keywords: dihydro pyrrole; cyclohexyl methoxyphenyl; propan cyclohexyl; nitrophenyl propan ... See more keywords
2-Methyl-4-(4-nitrophenyl)but-3-yn-2-ol: crystal structure, Hirshfeld surface analysis and computational chemistry study
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DOI: 10.1107/s2056989019010284
Abstract: In the title molecule, di-methylhydroxy and 4-nitrobenzene groups cap a central di-substituted acetylene residue. The extended structure features flattened, hexameric clusters sustained by hydroxy-O—H⋯O(hydroxy) hydrogen bonds. read more here.
Keywords: structure hirshfeld; methyl nitrophenyl; structure; crystal structure ... See more keywords