Mechanism analysis of transient ligand-induced β-C–H arylation of α-methyl pentanone
Sign Up to like & getrecommendations! Published in 2019 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-019-2523-1
Abstract: Based on a comprehensive DFT mechanism study, the reaction characteristics of β-C–H arylation of α-methyl pentanone with iodobenzene are revealed. In this reaction, glycine plays an important role as organic transient ligand, which can directly… read more here.
Keywords: arylation methyl; transient ligand; methyl pentanone; reaction ... See more keywords
Experimental and theoretical investigations of the kinetics and mechanism of the Cl + 4-hydroxy-4-methyl-2-pentanone reaction
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DOI: 10.1016/j.atmosenv.2017.07.038
Abstract: Abstract The reaction of 4-hydroxy-4-methyl-2-pentanone (4H4M2P) with Cl atoms was studied for the first time experimentally and theoretically. Relative kinetic measurements were carried out at room temperature and 1 bar of synthetic air/N 2 in two… read more here.
Keywords: methyl pentanone; rate; reaction; hydroxy methyl ... See more keywords