Novel copper(II) and zinc(II) complexes of halogenated bidentate N,O-donor Schiff base ligands: Synthesis, characterization, crystal structures, DNA binding, molecular docking, DFT and TD-DFT computational studies
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DOI: 10.1016/j.ica.2020.120004
Abstract: Abstract Eight novel complexes, including: [Cu(L1)2]: C1, [Cu(L2)2]: C2, [Cu(L3)2]: C3, [Cu(L4)2]: C4, [Zn(L1)2]: Z1, [Zn (L2)2]: Z2, [Zn (L3)2]: Z3, and [Zn (L4)2]: Z4, with four bidentate N,O-donor halogenated bis-Schiff base ligands (HL1: 4-Bromo-2-[(4-fluorophenylimino)… read more here.
Keywords: base ligands; methyl phenol; bidentate donor; geometry ... See more keywords
Synthesis and comparative study on the anti-corrosion potentials of some Schiff base compounds bearing similar backbone
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.11.161
Abstract: Abstract The synthesis of (E)-4-((p-tolylimino)methyl) phenol (TMPOL), (E)-4-((benzylimino)methyl) phenol (BMPOL) and (E)-4-((p-phenylimino)methyl) phenol (PMPOL) were carried out by the condensation reaction of 4-methylaniline, phenylmethanamine and aniline, respectively, with 4-hydroxybenzaldehyde. Molecular identities of the Schiff base… read more here.
Keywords: synthesis; methyl phenol; base compounds; schiff base ... See more keywords
Well-Defined and Highly Effective Nickel Catalysts Coordinated on Tridentate SNO Schiff-Base Derivatives for Alternating Copolymerization of Epoxides and Anhydrides.
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DOI: 10.1021/acs.inorgchem.2c03094
Abstract: A series of Ni complexes supported by SNO Schiff-base derivatives were synthesized in this study. Complex synthesis and characterization data are reported herein. Treatment of the pro-ligands [L1-H = 2-(((2-(methylthio)ethyl)imino)methyl)phenol, L2-H = 2,4-di-tert-butyl-6-(((2-(methylthio)ethyl)imino)methyl)phenol, L3-H =… read more here.
Keywords: ethyl imino; imino methyl; methylthio ethyl; methyl phenol ... See more keywords
Synthesis, quantum chemical calculations and molecular docking studies of 2-ethoxy-4[(2-trifluromethyl-phenylimino)methyl]phenol
Sign Up to like & getrecommendations! Published in 2020 at "Molecular Physics"
DOI: 10.1080/00268976.2020.1781945
Abstract: In the present work, the FT-IR, FT-Raman and UV-Vis spectra of 2-Ethoxy-4[(2-trifluromethyl-phenylimino)methyl]phenol (2E42TP) were recorded and analysed. The vibrational assignments of the present molecule were made on the basis of total energy distribution (TED) by… read more here.
Keywords: trifluromethyl phenylimino; phenylimino methyl; ethoxy trifluromethyl; docking studies ... See more keywords
The effect of ligand design on the structural and photophysical properties of Nd(III) complexes with Schiff bases of the [(phenylimino)methyl]phenol-type
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1750604
Abstract: Abstract Three mononuclear Nd(III) complexes [Nd(HL1)2(NO3)3] (1, HL1=2-methoxy-6-[(E)-(phenylimino)methyl]phenol), [Nd(HL2)3(NO3)3] (2, HL2=5-methoxy-2-[(E)-(phenylimino)methyl]phenol) and [Nd(HL3)2(NO3)3]·CH3OH (3, HL3=2-methoxy-6-{(E)-[(2-methoxyphenyl)imino]methyl}phenol) were prepared in a 1:3 ratio (M:L) in methanol. The effect of the ligand substituents and their positions (meta versus… read more here.
Keywords: phenylimino methyl; effect ligand; methyl phenol; chemistry ... See more keywords
Synthesis, antioxidant activity, and density functional theory study of some novel 4-[(benzo[d]thiazol-2-ylimino)methyl]phenol derivatives: a comparative approach for the explanation of their radical scavenging activities
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DOI: 10.4103/1735-5362.305187
Abstract: Background and purpose: Radicals produced by Fenton and Haber-Weiss reactions play detrimental roles in our body. Some oxidized proteins as toxic configurations are identified in amyloid-β deposits. These deposits mostly occur in conditions, such as… read more here.
Keywords: antioxidant activity; methyl phenol; benzo thiazol; thiazol ylimino ... See more keywords