Methyl-rotation dynamics in metal-organic frameworks probed with terahertz spectroscopy.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc02650e
Abstract: In ZIF-8 and its cobalt analogue ZIF-67, the imidazolate methyl-groups, which point directly into the void space, have been shown to freely rotate - even down to cryogenic temperatures. Using a combination of experimental terahertz… read more here.
Keywords: methyl rotation; rotation dynamics; dynamics metal; metal organic ... See more keywords
Internal methyl rotation and molecular structure of trifluorotoluenes: microwave rotational spectra of 2,3,4- and 2,4,5-trifluorotoluene
Sign Up to like & getrecommendations! Published in 2020 at "Canadian Journal of Physics"
DOI: 10.1139/cjp-2019-0477
Abstract: The microwave rotational spectra of 2,3,4- and 2,4,5-trifluorotoluenes, along with all 13C isotopic species in natural abundance, have been recorded in the frequency range 8–27 GHz employing pulsed... read more here.
Keywords: methyl rotation; molecular structure; internal methyl; microwave rotational ... See more keywords