Theoretical investigation on structural effects of Pt–Mn catalyst on activity and selectivity for methylcyclohexane dehydrogenation
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2018.09.026
Abstract: Abstract The structure of Pt-Mn/Al2O3 catalyst which shows high performance for dehydrogenation of methylcyclohexane, a prospective hydrogen carrier, was investigated by XAFS and DFT calculations. Mn addition on Pt/Al2O3 brings higher activity, selectivity, and stability… read more here.
Keywords: theoretical investigation; methylcyclohexane; activity selectivity; dehydrogenation ... See more keywords
Low-temperature selective dehydrogenation of methylcyclohexane by surface protonics over Pt/anatase-TiO2 catalyst
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.10.133
Abstract: Abstract For a liquid organic hydride system used for a hydrogen carrier, methylcyclohexane (MCH)–toluene cycle is promising. In this cycle, dehydrogenation of MCH is an endothermic reaction and a key step. We have conducted dehydrogenation… read more here.
Keywords: methylcyclohexane; dehydrogenation; tio2 catalyst; anatase tio2 ... See more keywords
Density functional theory study on catalytic dehydrogenation of methylcyclohexane on Pt(111)
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.12.096
Abstract: Abstract Density Functional Theory (DFT) method was used to study the step-by-step dehydrogenation of methylcyclohexane (MCH) to toluene on a Pt(111) surface to understand adsorption properties of the reactants, intermediates and the products involved. The… read more here.
Keywords: methylcyclohexane; density functional; dehydrogenation; dehydrogenation methylcyclohexane ... See more keywords
Density functional theory study on dehydrogenation of methylcyclohexane on Ni–Pt(111)
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2020.09.207
Abstract: Abstract Methylcyclohexane is a very promising liquid organic hydrogen carrier, but its dehydrogenation mechanism on Pt-based bimetallic catalysts is not yet clear. In order to understand the catalytic dehydrogenation of methylcyclohexane on Ni–Pt(111), DFT calculations… read more here.
Keywords: methylcyclohexane; density functional; dehydrogenation; methylcyclohexane 111 ... See more keywords
A study of methylcyclohexane cracking in a micro-channel reactor coated with M/SiO2 (M Fe, Co, Ni) catalysts under supercritical conditions
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Analytical and Applied Pyrolysis"
DOI: 10.1016/j.jaap.2019.104642
Abstract: Abstract A series of transition metals M (M = Fe, Co, Ni) modified SiO2 catalysts were prepared by sol-gel method and coated on the inner wall of stainless steel tubes, in order to develop the micro-channel reactors.… read more here.
Keywords: sio2 catalysts; micro channel; spectroscopy; supercritical conditions ... See more keywords
Size Distribution of Nascent Soot in Premixed n-Hexane, Cyclohexane, and Methylcyclohexane Flames
Sign Up to like & getrecommendations! Published in 2019 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.9b00904
Abstract: The evolution of particle size distribution function (PSDF) of nascent soot in premixed flames of n-hexane, cyclohexane, and methylcyclohexane was studied on the burner-stabilized stagnation flame platform. The cold gas velocities were changed to keep… read more here.
Keywords: flame; soot; methylcyclohexane; distribution ... See more keywords
Kinetics on NiZn Bimetallic Catalysts for Hydrogen Evolution via Selective Dehydrogenation of Methylcyclohexane to Toluene
Sign Up to like & getrecommendations! Published in 2017 at "ACS Catalysis"
DOI: 10.1021/acscatal.6b03299
Abstract: Liquid organic chemical hydrides are effective hydrogen storage media for easy and safe transport. The chemical couple of methylcyclohexane (MCH) and toluene (TOL) has been considered one of the feasible cycles for a hydrogen carrier,… read more here.
Keywords: toluene; methylcyclohexane; dehydrogenation; selective dehydrogenation ... See more keywords