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   Articles with "methylphosphonate" as a keyword



Dissolution of cotton cellulose in 1:1 mixtures of 1-butyl-3-methylimidazolium methylphosphonate and 1-alkylimidazole co-solvents.

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recommendations! Published in 2019 at "Carbohydrate polymers"

DOI: 10.1016/j.carbpol.2019.05.071

Abstract: During the past decade, ionic liquids (ILs) have attracted increasing attention as efficient, novel solvents for dissolving cellulose. In this study, 1-butyl-3-methylimdazolium methylphosphonate ([C4C1im][(OMe)(H)PO2]) was used in the dissolution of cotton cellulose and the role… read more here.

Keywords: microscopy; cotton cellulose; methylphosphonate; dissolution cotton ... See more keywords

A rational synthesis of ladder-like motif in zinc-methylphosphonate from a preformed coordination assembly

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recommendations! Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2018.07.016

Abstract: Abstract The study describes the synthesis of new hybrid zinc phosphonates, {Zn(O3PMe)(4,4′-bipy)0.5}·2H2O (2), {Zn(O3PMe)(1,2-bpe)0.5}·H2O (3) and Zn(O3PMe)(Im) (4) [4,4′-bipyridine (4,4′-bipy), 1,2-bis(4-pyridyl)ethane (1,2-bpe) and imidazole (Im)] by hydro(solvo)thermal reaction (140–150 °C, 3 days) of a preformed coordination polymer,… read more here.

Keywords: zinc; rational synthesis; methylphosphonate; ladder ... See more keywords

Fenton-Derived OH Radicals Enable the MPnS Enzyme to Convert 2-Hydroxyethylphosphonate to Methylphosphonate: Insights from Ab Initio QM/MM MD Simulations.

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recommendations! Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b02659

Abstract: The mechanism for dioxygen activation represents one of the core issues in metalloenzymes. In most cases, the activation of the O2 molecule requires additional electrons from an external reducant. However, nonheme hydroxyethylphosphonate dioxygenase (HEPD) and… read more here.

Keywords: hydroxyethylphosphonate; methylphosphonate; mpns enzyme; activation ... See more keywords

Structural basis for methylphosphonate biosynthesis

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recommendations! Published in 2017 at "Science"

DOI: 10.1126/science.aao3435

Abstract: A source of methane in the upper ocean Methane concentrations are high in oxygenated surface waters. Methylphosphonate (MPn) is a suggested source, but an enzyme that synthesizes Mpn (MPnS) has so far only been identified… read more here.

Keywords: ocean; methylphosphonate; methane; source methane ... See more keywords

Biocatalytic cascade for the synthesis of methylphosphonate from phosphoenolpyruvate

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recommendations! Published in 2025 at "Microbial Cell Factories"

DOI: 10.1186/s12934-025-02858-y

Abstract: Methylphosphonate (Mpn), a building block for complex organophosphonate, is utilized in pharmaceuticals, agriculture, and chemical industries. It also serves as a critical substrate for resolving the methane paradox in ecological studies. However, current Mpn synthesis… read more here.

Keywords: biocatalytic cascade; synthesis; phosphoenolpyruvate; methylphosphonate ... See more keywords