Solvent-free method to encapsulate polyoxometalate into metal-organic frameworks as efficient and recyclable photocatalyst for harmful sulfamethazine degrading in water
Sign Up to like & getrecommendations! Published in 2019 at "Applied Catalysis B: Environmental"
DOI: 10.1016/j.apcatb.2019.01.012
Abstract: Abstract Through a less-investigated in-situ hot-pressing synthesis method, the phosphotungstic acid H3PW12O40 (denoted as PW12) was rapidly incorporated into a metal-organic framework MFM-300(In) in a short time, affording novel PW12@MFM-300(In) composites. This solvent-free preparation process… read more here.
Keywords: pw12 mfm; method; metal organic; mfm 300 ... See more keywords
MFM-300: From air pollution remediation to toxic gas detection
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2018.10.025
Abstract: Abstract The chemically stable family of MOF materials (MFM-300) is reviewed in this contribution. This material was recently reported few years ago (2011) and promising environmental remediation applications have been already proposed to date. The… read more here.
Keywords: air pollution; remediation; pollution remediation; remediation toxic ... See more keywords
Direct Visualization of Supramolecular Binding and Separation of Light Hydrocarbons in MFM-300(In)
Sign Up to like & getrecommendations! Published in 2022 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.2c01097
Abstract: The purification of light olefins is one of the most important chemical separations globally and consumes large amounts of energy. Porous materials have the capability to improve the efficiency of this process by acting as… read more here.
Keywords: adsorption; visualization supramolecular; direct visualization; separation ... See more keywords
Modulating supramolecular binding of carbon dioxide in a redox-active porous metal-organic framework
Sign Up to like & getrecommendations! Published in 2017 at "Nature Communications"
DOI: 10.1038/ncomms14212
Abstract: Hydrogen bonds dominate many chemical and biological processes, and chemical modification enables control and modulation of host–guest systems. Here we report a targeted modification of hydrogen bonding and its effect on guest binding in redox-active… read more here.
Keywords: mfm 300; metal organic; co2; binding ... See more keywords
Developing a sustainable route to environmentally relevant metal–organic frameworks: ultra-rapid synthesis of MFM-300(Al) using microwave heating
Sign Up to like & getrecommendations! Published in 2019 at "Green Chemistry"
DOI: 10.1039/c9gc02375e
Abstract: The synthesis of MFM-300(Al) in aqueous conditions and 10 minutes using microwave heating is reported. The material produced exhibits significantly enhanced uptake of CO2, SO2, and NO2 compared to the 3-day solvothermal route. read more here.
Keywords: mfm 300; synthesis mfm; using microwave; microwave heating ... See more keywords
Gas-phase organometallic catalysis in MFM-300(Sc) provided by switchable dynamic metal sites.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06935k
Abstract: MFM-300(Sc) was explored as a catalyst for the gas-phase hydrogenation of acetone. The catalysis results support the presence of non-permanent open Sc(III) sites within the structure due to the requirement of Lewis acid sites for… read more here.
Keywords: gas phase; catalysis; phase organometallic; mfm 300 ... See more keywords