Enantioselective Michael Spirocyclization of Palladium Enolates
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DOI: 10.1021/acscatal.5c02758
Abstract: : We report an enantio-and diastereoselective Michael spirocyclization reaction of tetrasubstituted palladium enolates. This allows for the formation of adjacent all-carbon quaternary and tertiary stereocenters in good yield, dr, and ee. Various subsequent cyclization reactions… read more here.
Keywords: michael spirocyclization; enantioselective michael; palladium enolates;