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Published in 2017 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2016.09.135
Abstract: Abstract Microkinetic analysis of ethanol to 1,3-butadiene reactions over MgO-SiO 2 catalysts was performed based on the detailed characterization of experimental fluctuations, taking into account the influence of the reaction temperature and catalyst properties on…
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Keywords:
reactions mgo;
experimental fluctuations;
butadiene reactions;
microkinetic analysis ... See more keywords
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Published in 2019 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2019.04.033
Abstract: Abstract The kinetics of vapor-phase acetone hydrogenation were investigated over a Pt/SiO2 catalyst through a range of temperatures (303–435 K) and reactant partial pressures (pACE = 0.3–140 Torr, pH2 = 100–930 Torr). We compile macroscopically observable reaction orders, apparent barriers, kinetic isotope…
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Keywords:
acetone;
microkinetic analysis;
acetone hydrogenation;
rate control ... See more keywords
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Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.09.008
Abstract: Abstract By using a descriptor-based microkinetic analysis combined with results from density functional theory calculations over eight transition-metal (including Ni, Cu, Rh, Pd, Ag, Ir, Pt, and Au) terrace and stepped surfaces, intermetallic compounds have…
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Keywords:
based microkinetic;
propane dehydrogenation;
descriptor based;
microkinetic analysis ... See more keywords