Articles with "microkinetic analysis" as a keyword



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Microkinetic analysis of ethanol to 1,3-butadiene reactions over MgO-SiO2 catalysts based on characterization of experimental fluctuations

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Published in 2017 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2016.09.135

Abstract: Abstract Microkinetic analysis of ethanol to 1,3-butadiene reactions over MgO-SiO 2 catalysts was performed based on the detailed characterization of experimental fluctuations, taking into account the influence of the reaction temperature and catalyst properties on… read more here.

Keywords: reactions mgo; experimental fluctuations; butadiene reactions; microkinetic analysis ... See more keywords
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Microkinetic analysis of acetone hydrogenation over Pt/SiO2

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Published in 2019 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2019.04.033

Abstract: Abstract The kinetics of vapor-phase acetone hydrogenation were investigated over a Pt/SiO2 catalyst through a range of temperatures (303–435 K) and reactant partial pressures (pACE = 0.3–140 Torr, pH2 = 100–930 Torr). We compile macroscopically observable reaction orders, apparent barriers, kinetic isotope… read more here.

Keywords: acetone; microkinetic analysis; acetone hydrogenation; rate control ... See more keywords
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Rational design of intermetallic compound catalysts for propane dehydrogenation from a descriptor-based microkinetic analysis

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Published in 2021 at "Journal of Catalysis"

DOI: 10.1016/j.jcat.2021.09.008

Abstract: Abstract By using a descriptor-based microkinetic analysis combined with results from density functional theory calculations over eight transition-metal (including Ni, Cu, Rh, Pd, Ag, Ir, Pt, and Au) terrace and stepped surfaces, intermetallic compounds have… read more here.

Keywords: based microkinetic; propane dehydrogenation; descriptor based; microkinetic analysis ... See more keywords