A two-dimensional microporous metal–organic framework for highly selective adsorption of carbon dioxide and acetylene
Sign Up to like & getrecommendations! Published in 2017 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2017.04.025
Abstract: Abstract Solvothermal reaction of 3-aminoisonicotinic acid (Haina) and Cu(NO 3 ) 2 ·2.5H 2 O gave a novel two-dimensional (2D) microporous metal–organic framework, [Cu(aina) 2 (DMF)]·DMF ( 1 , DMF = N,N-dimethylformamide). Single-crystal X-ray crystallographic study of… read more here.
Keywords: dimensional microporous; framework; metal organic; two dimensional ... See more keywords
New challenge of microporous metal-organic frameworks for adsorption of hydrogen fluoride gas
Sign Up to like & getrecommendations! Published in 2017 at "Materials Letters"
DOI: 10.1016/j.matlet.2017.03.111
Abstract: Abstract To avoid the health threat and environmental pollution as well as to preserve the life of industrial equipment, it is very important and necessary to find an efficient method for detecting and eliminating HF… read more here.
Keywords: adsorption; challenge microporous; metal organic; gas ... See more keywords
Microporous metal–organic framework with open Cu2+ functional sites and optimized pore size for C2H2 storage and CH4 purification
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.08.056
Abstract: Abstract A microporous metal–organic framework (MOF), Cu6(ABTC)3(H2O)6·(DMA)7(H2O)12 (Cu-ABTC, H4ABTC = 3,3′,5,5′-azobenzenetetracarboxylic acid) was solvothermal obtained and structurally characterized. The activated Cu-ABTC-a exhibits high BET specific surface area of 2366 m2/g. Due to optimized pore space and open Cu2+… read more here.
Keywords: optimized pore; metal organic; ch4; microporous metal ... See more keywords
Sonochemically synthesized microporous metal–organic framework representing unique selectivity for detection of Fe3+ ions
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2018.11.062
Abstract: Abstract Synthesis of metal–organic framework (MOF) materials via ultrasound (US) irradiation involves shorter reaction times and offers enhanced control of particle size and morphology compared to conventional electric heating. Here, we report the exploration of… read more here.
Keywords: microporous metal; organic framework; fe3; metal organic ... See more keywords
A microporous metal-organic framework with a completely reversed adsorption relationship for C2 hydrocarbons at room temperature.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b22410
Abstract: As a new type porous material, metal-organic frameworks (MOFs) have been widely studied in gas adsorption and separation, especially in C2 hydrocarbons. Considering the stronger interaction between the unsaturated molecules and the metal sites, and… read more here.
Keywords: adsorption; metal organic; microporous metal; adsorption relationship ... See more keywords
A Microporous Metal-Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12068
Abstract: We demonstrate the assembly of a mononuclear metal center, a hexanuclear cluster, and a V-shaped, trapezoidal tetracarboxylate linker into a microporous metal-organic framework featuring an unprecedented 3-nodal (4,4,8)-c lyu topology. The compound, HIAM-302, represents the… read more here.
Keywords: secondary building; metal organic; microporous metal; metal ... See more keywords
A microporous metal-organic framework with naphthalene diimide groups for high methane storage.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01911a
Abstract: We reported a microporous MOF FJU-101 with open naphthalene diimide functional groups for room temperature (RT) high methane storage. At RT and 65 bar, the total volumetric CH4 storage capacity of 212 cm3 (STP) cm-3… read more here.
Keywords: storage; methane storage; naphthalene diimide; high methane ... See more keywords
Fragmented α-Amylase into Microporous Metal-Organic Frameworks as Bioreactors
Sign Up to like & getrecommendations! Published in 2021 at "Materials"
DOI: 10.3390/ma14040870
Abstract: This work presents an efficient and facile strategy to prepare an α-amylase bioreactor. As enzymes are quite large to be immobilized inside metal-organic frameworks (MOFs), the tertiary and quaternary structures of α-amylase were first disrupted… read more here.
Keywords: metal organic; microporous metal; fragmented amylase; organic frameworks ... See more keywords