Macroscale Conjugated Microporous Polymers: Controlling Versatile Functionalities Over Several Dimensions
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202104952
Abstract: Since discovered in 2007, conjugated microporous polymers (CMPs) have been developed for numerous applications including gas adsorption, sensing, organic and photoredox catalysis, energy storage, etc. While featuring abundant micropores, the structural rigidity derived from CMPs’… read more here.
Keywords: conjugated microporous; polymers controlling; macroscale conjugated; microporous polymers ... See more keywords
Perylene-Containing Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201700049
Abstract: Three perylene-containing conjugated microporous polymers (PrCMPs) are synthesized via Suzuki–Miyaura cross-coupling reaction from perylene with four polymerizable functional groups and a range of different substituted benzene derivatives. The pore property and bandgap of the resulting… read more here.
Keywords: containing conjugated; hydrogen evolution; geometry; microporous polymers ... See more keywords
Carbazolic Conjugated Microporous Polymers for Photocatalytic Organic Transformations.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300012
Abstract: Heterogeneous photocatalysis have been deemed as a versatile and colorful platform for exploring efficient transformation systems. Henceforth, the design of photocatalysts underpin a wide range of research interests. By virtue of synthetic versatility, stability, non-toxicity,… read more here.
Keywords: conjugated microporous; photocatalytic organic; carbazolic conjugated; microporous polymers ... See more keywords
Thiophene-based conjugated microporous polymers: synthesis, characterization and efficient gas storage
Sign Up to like & getrecommendations! Published in 2017 at "Science China Chemistry"
DOI: 10.1007/s11426-017-9069-6
Abstract: A series of thiophene-based conjugated microporous polymers (ThPOPs) have been synthesized on the basis of ferric chloride-catalyzed oxidative coupling polymerization of multi-thienyl monomers. The structures of ThPOPs were confirmed via solid-state 13C CP/MAS NMR spectroscopy… read more here.
Keywords: thiophene based; efficient gas; microporous polymers; spectroscopy ... See more keywords
Electrically conductive conjugate microporous polymers (CMPs) via confined polymerization of pyrrole for electromagnetic wave absorption
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2020.125591
Abstract: Abstract Endowing conjugate microporous polymers (CMPs) with appropriate electrical conductivity greatly expands the application scope of CMPs, especially in electronic-related applications. In this paper, we report a strategy to prepare electrically conductive CMPs via confined… read more here.
Keywords: absorption; cmps via; conjugate microporous; polymers cmps ... See more keywords
Structural effects of microporous polymers on adsorption/separation of C1-C3 light hydrocarbons and CO2 in natural gas
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.131985
Abstract: Abstract Microporous polymers (PAN-T1 and PAN-T2) with the similar polymer skeleton but considerably different BET surface areas from 1106 to 1563 m2 g-1, micropore surface areas from 250 to 868 m2 g-1 and total pore… read more here.
Keywords: co2; light hydrocarbons; c2h6; microporous polymers ... See more keywords
Synthesis of conjugated microporous polymers based on θ-Al2O3 substrate for enhanced iodine capture
Sign Up to like & getrecommendations! Published in 2020 at "Materials Letters"
DOI: 10.1016/j.matlet.2020.128588
Abstract: Abstract Conjugated microporous polymer (CMPs) is a new subclass of porous organic materials with extended π-electron conjugated structures. Three new CMPs 33%Al2O3@CMP-1, 2, and 3 were synthesized based on θ-Al2O3 by the Schiff reaction. Their… read more here.
Keywords: synthesis conjugated; cmp; based al2o3; polymers based ... See more keywords
Ultrastable luminescent hybrid microporous polymers based on polyhedral oligomeric silsesquioxane for CO2 uptake and metal ion sensing
Sign Up to like & getrecommendations! Published in 2021 at "Microporous and Mesoporous Materials"
DOI: 10.1016/j.micromeso.2020.110695
Abstract: Abstract In this study we prepared four different fluorescent hybrid microporous polymers (HPPs) derived from cubic octavinylsilsesquioxane (OVS) through Heck coupling with brominated anthracene (An-Br2), triphenyltriazine (TPT-Br3), bicarbazole (Car-Br4) and tetraphenylethene (TPE-Br4). The chemical structures… read more here.
Keywords: hybrid microporous; ion sensing; microporous polymers; spectroscopy ... See more keywords
Conjugated microporous polymers bearing isocyanurate moiety as efficient antibacterial membrane and aerogels
Sign Up to like & getrecommendations! Published in 2020 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2020.117020
Abstract: Abstract The development of high-performance antibacterial materials is of great importance for human survival and health. Herein, we report the exploitation of novel conjugated microporous polymers bearing isocyanurate moiety (I-CMPs), which were synthesized using trichloroisocyanuric… read more here.
Keywords: bearing isocyanurate; efficient antibacterial; microporous polymers; isocyanurate moiety ... See more keywords
Advances in Conjugated Microporous Polymers
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Reviews"
DOI: 10.1021/acs.chemrev.9b00399
Abstract: Conjugated microporous polymers (CMPs) are a unique class of materials that combine extended π-conjugation with a permanently microporous skeleton. Since their discovery in 2007, CMPs have become established as an important subclass of porous materials.… read more here.
Keywords: advances conjugated; microporous polymers; conjugated microporous;
Conjugated Microporous Polymers with Extended π-Structures for Organic Vapor Adsorption
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b02515
Abstract: Conjugated microporous polymers (CMPs), which are organic porous materials with π-conjugated skeletons, have attracted considerable attention in recent years owing to their distinct properties. Here, two sp2 carbon CMPs with analogous structures, namely, BO-CMP-1 and… read more here.
Keywords: polymers extended; cmp; structures organic; microporous polymers ... See more keywords