Visible-light-induced radical 1,2-aryl migration in diaryl allyl alcohols for efficient synthesis of 1,5-dicarbonyl compounds.
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DOI: 10.1039/d5cc02799c
Abstract: Herein, we developed a protocol for Ir(III)-photocatalyzed, visible-light-driven radical 1,2-aryl migration in diaryl allyl alcohols, leading to the formation of 1,5-dicarbonyl compounds under additive-free conditions, with broad substrate tolerance. Electron-deficient aryl groups exhibit enhanced migration… read more here.
Keywords: migration diaryl; migration; visible light; radical aryl ... See more keywords