Radical-mediated remote migration of quinoxalinones.
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DOI: 10.1039/d2cc06887g
Abstract: Disclosed herein is the first example of radical-mediated remote migration of quinoxalinones. The quinoxalinonyl-functionalization of alkenes employs the quinoxalinone-substituted tertiary bishomoallylic alcohols as substrates, proceeds through intramolecular 1,4-quinoxalinone migration, and gives rise to complex γ-quinoxalinone-substituted… read more here.
Keywords: remote migration; mediated remote; migration quinoxalinones; migration ... See more keywords