The Milstein Bipyridyl PNN Pincer Complex of Ruthenium Becomes a Noyori-Type Catalyst under Reducing Conditions.
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DOI: 10.1021/jacs.0c06518
Abstract: Hydrogenation of the dearomatized PNN ligand of the Milstein bipyridyl complex RuH(CO)[PNN] (2) gives a square-pyramidal Ru(II) product RuH(CO)[pPNN] (5). The central ring of the pPNN ligand is a piperidine. A minor byproduct of the… read more here.
Keywords: bipyridyl pnn; milstein bipyridyl; pnn ligand; pnn ... See more keywords