Ring-Opening Polymerization of ε-Caprolactone by Using Aluminum Complexes Bearing Aryl Thioether Phenolates: Labile Thioether Chelation.
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DOI: 10.1021/acs.inorgchem.1c03683
Abstract: In this study, aluminum complexes bearing ferrocene-based and arylthiomethylphenolate ligands were synthesized, and their catalytic activity for ε-caprolactone (CL) polymerization was investigated. The catalytic activity of the reduced form of Al complexes was higher than… read more here.
Keywords: aluminum complexes; form; min conversion; complexes bearing ... See more keywords