Articles with "mixed linker" as a keyword



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Tuning Hydrophilicity of Aluminum MOFs by a Mixed-Linker Strategy for Enhanced Performance in Water Adsorption-Driven Heat Allocation Application.

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Published in 2023 at "Advanced science"

DOI: 10.1002/advs.202301311

Abstract: Water adsorption-driven heat transfer (AHT) technology has emerged as a promising solution to address crisis of the global energy consumption and environmental pollution of current heating and cooling processes. Hydrophilicity of water adsorbents plays a… read more here.

Keywords: mofs; mixed linker; water; linker ... See more keywords
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Solid-Solution Mixed-Linker Synthesis of Isoreticular Al-Based MOFs for an Easy Hydrophilicity Tuning in Water-Sorption Heat Transformations

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Published in 2019 at "Chemistry of Materials"

DOI: 10.1021/acs.chemmater.9b00617

Abstract: The solid-solution mixed-linker approach, where a linker is partially replaced by a similar one under retention of the isoreticular metal–organic framework (MOF) structure, offers an easy and inexp... read more here.

Keywords: mixed linker; linker synthesis; solid solution; solution mixed ... See more keywords
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Tuning the Structures of Metal–Organic Frameworks via a Mixed-Linker Strategy for Ethylene/Ethane Kinetic Separation

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Published in 2020 at "Chemistry of Materials"

DOI: 10.1021/acs.chemmater.9b04177

Abstract: A mixed linker strategy has led to the discovery of the new metal–organic framework material, GT-18 (GT = Georgia Tech), which has no open metal sites and a chiral structure. The material includes ... read more here.

Keywords: mixed linker; metal organic; tuning structures; linker strategy ... See more keywords
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Imparting Multifunctionality in Zr-MOFs Using the One-Pot Mixed-Linker Strategy: The Effect of Linker Environment and Enhanced Pollutant Removal.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c03607

Abstract: The development of mixed-linker metal-organic frameworks (MOFs) is an efficient strategy to improve the performance of MOFs. Herein, we successfully integrate tetrakis(4-carboxyphenyl)porphyrin (TCPP) into different Zr-MOFs via a facile one-pot solvothermal synthesis while preserving the… read more here.

Keywords: mofs; mixed linker; linker; pcn 777 ... See more keywords
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Tuning Thermal Expansion in Metal-Organic Frameworks using a Mixed Linker Solid Solution Approach.

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Published in 2019 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b06109

Abstract: Several metal-organic frameworks are known to display negative thermal expansion (NTE). However, unlike traditional NTE material classes, there have been no reports where the thermal expansion of a MOF has been tuned continuously from negative… read more here.

Keywords: mixed linker; organic frameworks; expansion; metal organic ... See more keywords
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Antibiotic-triggered reversible luminescence switching in amine-grafted mixed-linker MOF: exceptional turn-on and ultrafast nanomolar detection of sulfadiazine and adenosine monophosphate with molecular keypad lock functionality

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Published in 2019 at "Journal of Materials Chemistry A"

DOI: 10.1039/c9ta06632b

Abstract: Mixed-linker CSMCRI-2 demonstrates the turn-on and nanomolar detection of antibiotics and biophosphates with antibiotic-triggered reversible fluorescence switching and keypad lock function. read more here.

Keywords: antibiotic triggered; mixed linker; keypad lock; triggered reversible ... See more keywords
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The introduction of functional side groups and the application of the mixed-linker concept in divalent MIL-53(Ni) materials.

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Published in 2020 at "Dalton transactions"

DOI: 10.1039/d0dt01222j

Abstract: Metal-organic framework materials with functional side groups are commonly used for various purposes like post-synthetic modification reactions or the tuning of pore geometries. Additionally, the mixed-linker concept, in which different linkers are statistically distributed over… read more here.

Keywords: mixed linker; functional side; mil materials; linker ... See more keywords
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Fabricating defect-rich metal-organic frameworks via mixed linker-induced crystal transformation.

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Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc00923d

Abstract: Defect-rich hcp UiO-66-NO2 was synthesized via mixed linker-induced crystal transformation from fcu UiO-66-NO2/NH2. The defect concentration and porosity of hcp UiO-66-NO2 can be fine-tuned by varying the BDC-NH2/BDC-NO2 ratio, which in turn endowed hcp UiO-66-NO2… read more here.

Keywords: via mixed; mixed linker; defect rich; linker induced ... See more keywords
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Transformation of a copper-based metal-organic polyhedron into a mixed linker MOF for CO2 capture.

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Published in 2023 at "Dalton transactions"

DOI: 10.1039/d2dt04162f

Abstract: A new mixed linker metal-organic framework (MOF) has been synthesized from a copper-based metal-organic polyhedron (MOP-1) and 2,2'-bipyridine (2,2'-bipy). The CuMOF-Bipy with a formula of [Cu2(2,2'-bpy)2(m-BDC)2]n is comprised of a binuclear Cu(II) node coordinated to… read more here.

Keywords: mixed linker; metal organic; based metal; copper based ... See more keywords