Synthesis of Mixed Phosphine–Phosphine Oxide Ligands by Rh(I)‐Catalyzed C─H Bond Alkylation
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202500639
Abstract: The design of phosphine ligands is pivotal in transition metal catalysis, enabling fine‐tuning of catalytic activity, selectivity, and stability. Hemilabile ligands, particularly mixed phosphine–phosphine oxide ligands, offer dynamic coordination, stabilizing reactive intermediates, and enhancing catalytic… read more here.
Keywords: phosphine; oxide ligands; phosphine phosphine; mixed phosphine ... See more keywords
Synthesis and structural characterization of new heteroleptic copper(I) complexes based on mixed phosphine/thiocarbamoyl-pyrazoline ligands
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DOI: 10.1016/j.poly.2016.10.003
Abstract: Abstract Two novel mononuclear heteroleptic Cu(I) complexes based on mixed phosphine/thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized. For both complexes, similar structural behavior was observed around Cu(I) atoms, which exhibited a distorted tetrahedral coordination geometry… read more here.
Keywords: based mixed; thiocarbamoyl pyrazoline; mixed phosphine; complexes based ... See more keywords