Tuning Au(I)···Tl(I) Interactions via Mixed Thia-Aza Macrocyclic Ligands: Effects on the Structural and Luminescence Properties.
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DOI: 10.1021/acs.inorgchem.7b02035
Abstract: Reaction of the heterometallic complexes [{Au(C6X5)2}Tl]n (X = Cl, F) with equimolecular amounts of the N,S-mixed-donor crown ethers [12]aneNS3 or [12]aneN2S2 affords the new Au(I)/Tl(I) derivatives [{Au(C6Cl5)2}{Tl(L)}2][Au(C6Cl5)2] [L = [12]aneNS3 (1), [12]aneN2S2 (2)], [{Au(C6F5)2}Tl([12]aneNS3)]2 (3),… read more here.
Keywords: mixed thia; tuning interactions; via mixed; thia aza ... See more keywords