Rosmarinus officinalis directed palladium nanoparticle synthesis: Investigation of potential anti-bacterial, anti-fungal and Mizoroki-Heck catalytic activities
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Powder Technology"
DOI: 10.1016/j.apt.2020.01.024
Abstract: Abstract The present work was aimed to account a green and eco-friendly synthesis of palladium nanoparticles using Rosmarinus officinalis leaves extracts for the first time, therefore, that can be an acceptable replacement for chemical media… read more here.
Keywords: rosmarinus officinalis; palladium nanoparticles; anti fungal; palladium ... See more keywords
Basketing nanopalladium into calix[4]pyrrole as an efficient catalyst for Mizoroki-Heck reaction
Sign Up to like & getrecommendations! Published in 2017 at "Arabian Journal of Chemistry"
DOI: 10.1016/j.arabjc.2016.06.019
Abstract: Abstract An approach to synthesize calix[4]pyrrole protected palladium nanoparticles (PdNPs) employed for catalytic Mizoroki-Heck C-C coupling reaction is reported. The nanoparticles are synthesized in water using novel calix[4]pyrrole tetrahydrazide (CPTH) as a reducing as well… read more here.
Keywords: heck; calix pyrrole; reaction; mizoroki heck ... See more keywords
The effect of framework functionality on the catalytic activation of supported Pd nanoparticles in the Mizoroki–Heck coupling reaction
Sign Up to like & getrecommendations! Published in 2017 at "Comptes Rendus Chimie"
DOI: 10.1016/j.crci.2016.06.002
Abstract: Abstract Palladium nanoparticles (Pd-NPs) were supported on functional and nonfunctional Co-coordination polymers (Pd/CoBDCNH2 and Pd/CoBDC). Advanced analytical techniques revealed that Pd-NPs are supported on the external surface of the polymer framework and the functionalized framework… read more here.
Keywords: framework functionality; framework; effect framework; reaction ... See more keywords
Palladium–N-heterocyclic carbene complexes for the Mizoroki–Heck reaction: An appraisal
Sign Up to like & getrecommendations! Published in 2017 at "Comptes Rendus Chimie"
DOI: 10.1016/j.crci.2017.03.003
Abstract: Abstract This article presents a review of the most significant developments with N-heterocyclic carbene (NHC)–palladium catalytic systems used for the Heck reaction. For more than the past two decades, a large number of new NHC–Pd… read more here.
Keywords: metal; reaction; palladium; heck reaction ... See more keywords
Synthesis of nano magnetic supported NHC-palladium and investigation of its applications as a catalyst in the Mizoroki-Heck cross-coupling reaction in H2O
Sign Up to like & getrecommendations! Published in 2020 at "Heliyon"
DOI: 10.1016/j.heliyon.2020.e04946
Abstract: The unique properties of N-heterocyclic carbenes (NHCs) as an effective ligand for palladium catalytic centers have recently found much attention. In this work, Fe3O4 nanoparticle supported palladium(II)–N-heterocyclic carbene catalyst was successfully designed, synthesized and characterized… read more here.
Keywords: coupling reaction; cross coupling; heck cross; reaction ... See more keywords
Ligand-free palladium-catalyzed Mizoroki-Heck reaction to synthesize valuable α-trifluoromethylacrylates
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2020.109483
Abstract: Abstract α-Trifluoromethylacrylates were synthesized using efficient ligand-free palladium catalyzed Mizoroki-Heck reaction. With the alkyl trifluoromethylacrylates used as substrates, different catalytic systems were explored including Pd/C as a catalyst. Good to excellent yields were obtained with… read more here.
Keywords: catalyzed mizoroki; ligand free; palladium catalyzed; heck reaction ... See more keywords
N-heterocyclic carbene palladium complexes with different N-coordinated ligands: Comparison of their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactions
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114271
Abstract: Abstract In this paper, we have reported the synthesis and catalytic activities of four new anthracene substituted imidazole-based palladium N-heterocyclic carbene complexes. The synthesized complexes, 2a–d, were stabilized with different N-heterocycles, namely pyridine, N-methylimidazole, N-vinylimidazole… read more here.
Keywords: suzuki miyaura; catalytic activities; mizoroki heck; heterocyclic carbene ... See more keywords
Synthesis of new adamantyl-imine palladium(II) complexes and their application in Mizoroki-Heck and Suzuki-Miyaura C C cross-coupling reactions
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115280
Abstract: Abstract Improving carbon–carbon cross-coupling reactions is an ongoing process and finding the most versatile and stable catalyst precursors has been of great interest. Ligand design has been proven to be important since it is responsible… read more here.
Keywords: suzuki miyaura; coupling reactions; cross coupling; mizoroki heck ... See more keywords
First Cp*Co(III)-catalyzed Mizoroki-Heck coupling reactions of alkenes and aryl bromide/iodide
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2019.151283
Abstract: Abstract A Cp*Co(CO)I2 catalyzed Mizoroki-Heck coupling of alkenes and aryl halide is established at feasible reaction conditions. The Cp*Co(III) catalyst excellently work to couple the aryl iodide and alkene, and produce up to 94% yield… read more here.
Keywords: catalyzed mizoroki; heck coupling; alkenes aryl; heck ... See more keywords
Detection and Structural Investigation of Elusive Palladium Hydride Intermediates Formed from Simple Metal Salts.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00173
Abstract: The Mizoroki-Heck reaction is one of the most known and best studied catalytic transformations and has provided an outstanding driving force for the development of catalysis and synthetic applications. Three out of four classical Mizoroki-Heck… read more here.
Keywords: palladium hydride; hydride intermediates; palladium; heck reaction ... See more keywords
A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00184
Abstract: Metal complexes bearing N-heterocyclic carbene (NHC) ligands are typically considered the system of choice for homogeneous catalysis with well-defined molecular active species due to their stable metal–ligand framework. A detailed study involving 19 different Pd-NHC… read more here.
Keywords: new mode; metal; nhc systems; heck reaction ... See more keywords