Secondary Coordination Sphere‐Directed Design of Thermo‐Responsive and Bright Luminescent Manganese(II) Complexes
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DOI: 10.1002/adom.202502008
Abstract: Luminescent MnII complexes have attracted considerable attention as low‐cost and earth‐abundant alternatives to precious metal‐based emitters. However, their development is limited by certain challenges, including severe thermal quenching, moisture sensitivity, and a lack of efficient… read more here.
Keywords: mnii complexes; secondary coordination; coordination sphere; luminescent ... See more keywords
Steric control of dioxygen activation pathways for MnII complexes supported by pentadentate, amide-containing ligands.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02682g
Abstract: Dioxygen activation at manganese centers is well known in nature, but synthetic manganese systems capable of utilizing O2 as an oxidant are relatively uncommon. These present investigations probe the dioxygen activation pathways of two mononuclear… read more here.
Keywords: mnii complexes; dioxygen activation; activation pathways; mnii ... See more keywords