MnIV-Oxo complex of a bis(benzimidazolyl)-containing N5 ligand reveals different reactivity trends for MnIV-oxo than FeIV-oxo species.
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DOI: 10.1039/c9dt00308h
Abstract: Using the pentadentate ligand (N-bis(1-methyl-2-benzimidazolyl)methyl-N-(bis-2-pyridylmethyl)amine, 2pyN2B), presenting two pyridyl and two (N-methyl)benzimidazolyl donor moieties in addition to a central tertiary amine, new MnII and MnIV-oxo complexes were generated and characterized. The [MnIV(O)(2pyN2B)]2+ complex showed spectroscopic… read more here.
Keywords: oxo; mniv 2pyn2b; bis; oxo complexes ... See more keywords
Differences in chemoselectivity in olefin oxidation by a series of non-porphyrin manganese(IV)-oxo complexes.
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DOI: 10.1039/d2dt00876a
Abstract: High valent metal-oxo intermediates are versatile oxidants known to facilitate both oxygen atom transfer (OAT) and hydrogen atom transfer (HAT) reactions in nature. In addition to performing essential yet challenging biological reactions, these intermediates are… read more here.
Keywords: oxidation; mniv oxo; chemoselectivity; oxo ... See more keywords