α-γ-Type [Mo8O26]4--Containing Metal-Organic Complex Possessing Efficient Catalytic Activity toward the Oxidation of Thioether Derivatives.
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DOI: 10.1021/acs.inorgchem.0c03738
Abstract: In this work, a new α-γ-type [Mo8O26]4- anion was first synthesized and characterized by single-crystal X-ray diffraction analysis and was obtained by introducing molybdate to the synthesis of metal-organic complex (MOC) under hydrothermal conditions. An… read more here.
Keywords: mo8o26; efficient catalytic; metal organic; oxidation thioether ... See more keywords
Novel polyoxometalate-based cobalt complexes based on rigid pyridyl-triazole-tetrazole and pyridyl-bis(triazole) ligands
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DOI: 10.1039/c8ce01158c
Abstract: Three novel polyoxometalate (POM)-based metal–organic complexes (MOCs) constructed from rigid pyridyl-triazole-tetrazole and pyridyl-bis(triazole) ligands have been hydrothermally synthesized and structurally characterized: [Co3(Htyptz)2(γ-Mo8O26)(H2O)6]·4H2O (1), H2[Co3(Htyptz)2(TeMo6O24)(H2O)8]·6H2O (2), [Co3(Hpyttz)2(γ-Mo8O26)(H2O)8]·2H2O (3) (H2typtz = 3-(tetrazol-5-yl)-5-(pyrid-3-yl)-1,2,4-triazolyl, H2pyttz = 3-(pyrid-4-yl)-5-(1H-1,2,4-triazol-3-yl)-1,2,4-triazolyl). Single-crystal X-ray… read more here.
Keywords: rigid pyridyl; pyridyl triazole; mo8o26; metal organic ... See more keywords
Multi-functional photoelectric sensors based on a series of isopolymolybdate-based compounds for detecting different ions
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry frontiers"
DOI: 10.1039/d0qi00505c
Abstract: Five new polyoxometalate(POM)-based compounds, namely [CuII4(btmc)(ctcm)4(β-Mo8O26)]·[β-Mo8O26]·H2O (1), [CuII4(mct)2(ctcm)2(H2O)6(β-Mo8O26)]·[β-Mo8O26] (2), [CuII(dm4bt)(Mo3O10)] (3), [CoII(dm4bt)(Mo2O7)] (4) and [CoII(H2bdpm)(Mo2O7)] (5) (btmc = 1,4-bis(1,2,4-triazol-1-methyl)cyclohexane, mct = 4-(4-methyl-cyclohexylmethyl)-4H-[1,2,4]triazole, ctcm = C-(4-[1,2,4]triazol-4-ylmethyl-cyclohexyl)-methylamine, dm4bt = 2,2′-dimethyl-4,4′-bithiazole, and H2bdpm = 1,1′-bis(3,5-dimethyl-1H-pyrazolate)methane), were obtained through… read more here.
Keywords: mo8o26; functional photoelectric; multi functional; series ... See more keywords