Articles with "model compound" as a keyword



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Cleavage of an RNA Model Compound by an Arylmercury Complex

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Published in 2021 at "Chembiochem"

DOI: 10.1002/cbic.202000799

Abstract: A water‐soluble arylmercury complex has been synthesized, and its ability to catalyze the cleavage of the phosphodiester linkage of the RNA model compound adenylyl‐3′,5′‐(2′,3′‐O‐methyleneadenosine) has been assessed over a pH range of 3–8.5 and a… read more here.

Keywords: arylmercury complex; cleavage; model compound; rna model ... See more keywords
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Photocatalytic Degradation of β-O-4 Lignin Model Compound by In2S3 Nanoparticles Under Visible Light Irradiation

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Published in 2017 at "BioEnergy Research"

DOI: 10.1007/s12155-017-9886-8

Abstract: Cleaving the abundant β-O-4 linkages in lignin is a key issue for producing value-added products by controlled lignin depolymerization. Herein, hydrothermally synthesized In2S3 nanoparticles were primarily used to photodegrade guaiacylglycerol-β-guaiacyl ether, a β-O-4 lignin model… read more here.

Keywords: in2s3 nanoparticles; lignin model; model compound;
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Catalytic co-aromatization of methane and heptane as an alkane model compound over Zn-Ga/ZSM-5: A mechanistic study

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Published in 2018 at "Applied Catalysis B: Environmental"

DOI: 10.1016/j.apcatb.2018.05.006

Abstract: Abstract The joint conversion of methane and heptane, a model compound of paraffin-rich raffinate oil, over a Zn-Ga modified zeolite catalyst has been investigated at various reaction times. In comparison with the performance from a… read more here.

Keywords: methane; methane heptane; model compound; aromatization ... See more keywords
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Effects of inherent potassium on the catalytic performance of Ni/biochar for steam reforming of toluene as a tar model compound

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Published in 2020 at "Chinese Journal of Chemical Engineering"

DOI: 10.1016/j.cjche.2020.06.010

Abstract: Abstract Biochar supported nickel (Ni/BC) has been widely studied as a cheap and easy-to-prepare catalyst with potential applications in tar reforming during the gasification of low-rank fuels, such as brown coal and biomass. However, the… read more here.

Keywords: model compound; biochar; tar model; reforming toluene ... See more keywords
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Investigation of Ni/Fe/Mg zeolite-supported catalysts in steam reforming of tar using simulated-toluene as model compound

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Published in 2018 at "Fuel"

DOI: 10.1016/j.fuel.2017.09.051

Abstract: Abstract Catalytic performance of Ni/zeolite, Ni-Fe/zeolite, and Ni-Fe-Mg/zeolite catalysts were investigated in steam reforming of toluene as a biomass tar model compound to explore promotional effect of MgO and Fe on Ni/zeolite support. The Ni-Fe-Mg/zeolite… read more here.

Keywords: zeolite; tar; model compound; steam reforming ... See more keywords
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Model compound of [FeFe]-hydrogenase active site employing [2Fe–2S] subunit as non-innocent [4Fe–4S] cluster and its proton reduction performance

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Published in 2020 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2020.02.084

Abstract: Abstract Synthesis of model compound of [FeFe]-hydrogenase active site is a promising and effective method to produce hydrogen. [μ-(SCH(CH2CH3)CH2S)–Fe2(CO)5]2-(κ1-DPPE) (compound 1) and [μ-(SCH(CH2CH3)CH2S)] Fe2(CO)5 (κ1-DPPM) (compound 2) were designed and synthesized. Compared 1 and 2… read more here.

Keywords: reduction; model compound; compound fefe; proton reduction ... See more keywords
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Effect of kaolinites modified with Zr and transition metals on the pyrolysis behaviors of low-rank coal and its model compound

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Published in 2021 at "Journal of The Energy Institute"

DOI: 10.1016/j.joei.2020.11.009

Abstract: Abstract Acid treated kaolinites (KA) were successively loaded with Zr and Fe, Ni or Co component to control the product distribution and upgrade the tar quality in coal pyrolysis. The structure of the resultant catalysts… read more here.

Keywords: model compound; pyrolysis; low rank; rank coal ... See more keywords
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Rare Earth/Transition Metal Oxides for Syngas Tar Reforming: A Model Compound Study

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Published in 2018 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.8b00682

Abstract: A major problem in biomass or coal gasification is removal of syngas byproducts such as H2S, NH3, and tars (heavy hydrocarbons) that cause catalyst deactivation and clogging problems downstream. Rare earth oxides (REOs) doped with… read more here.

Keywords: model compound; tar reforming; rare earth; syngas ... See more keywords
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A model compound for pyridinechalcone-based multistate systems. Ring opening-closure as the slowest kinetic step of the multistate

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Published in 2019 at "New Journal of Chemistry"

DOI: 10.1039/c9nj04776j

Abstract: Amino-substituted pyridinechalcones configure multistate systems where a new type of flavylium derivative with potential biological activity are present. read more here.

Keywords: multistate systems; model compound; compound pyridinechalcone; pyridinechalcone based ... See more keywords

Relevant aspects of the conversion of guaiacol as a model compound for bio-oil over supported molybdenum oxycarbide catalysts

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Published in 2020 at "New Journal of Chemistry"

DOI: 10.1039/d0nj02531c

Abstract: Molybdenum supported over activated carbon has been carburized under carbothermal hydrogen reduction conditions at different temperatures in order to modify the carburization degree. The resulting catalysts were characterized by N2 physisorption, CO chemisorption, XPS, TPR,… read more here.

Keywords: oxycarbide; model compound; guaiacol; molybdenum ... See more keywords
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A Model of Compound Heterozygous, Loss-of-Function Alleles Is Broadly Consistent with Observations from Complex-Disease GWAS Datasets

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Published in 2017 at "PLoS Genetics"

DOI: 10.1371/journal.pgen.1006573

Abstract: The genetic component of complex disease risk in humans remains largely unexplained. A corollary is that the allelic spectrum of genetic variants contributing to complex disease risk is unknown. Theoretical models that relate population genetic… read more here.

Keywords: model compound; complex disease; disease risk; disease ... See more keywords