IrIII/NiII-Metallaphotoredox catalysis: the oxidation state modulation mechanism versus the radical mechanism.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc03550d
Abstract: A novel oxidation state modulation mechanism, merging oxidative quenching (IrIII-*IrIII-IrIV-IrIII) and nickel catalytic (NiII-NiI-NiIII-NiI-NiII) cycles, has been illuminated unambiguously for photoredox-mediated iridium(iii)/nickel(ii) dual catalyzed C-O cross-coupling of aryl bromide and alcohol. Quinuclidine participates in a… read more here.
Keywords: modulation mechanism; oxidation state; mechanism; state modulation ... See more keywords