A chiral salen-based MOF catalytic material with high thermal, aqueous and chemical stabilities.
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DOI: 10.1039/c7dt01116d
Abstract: A highly stable chiral salen-based metal-organic framework [(Cu4I4)2L4]·20DMF·3CH3CN (1) [L = (R,R)-N,N'-bis(3-tert-butyl-5-(4-pyridyl)salicylidene)-1,2-diphenylethylenediamine nickel(ii)] has been synthesized and characterized by single crystal X-ray diffraction and other physicochemical methods. 1 exhibits a rare 8-fold interpenetrated 3D framework… read more here.
Keywords: mof catalytic; salen based; solution; catalytic material ... See more keywords
Greener synthesis of Cu-MOF-74 and its catalytic use for the generation of vanillin.
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DOI: 10.1039/c7dt04701k
Abstract: A greener synthesis of Cu-MOF-74 was obtained, for the first time, in methanol as the unique solvent and at room temperature. Full characterisation of the MOF material showed its purity and also its nanocrystalline nature.… read more here.
Keywords: synthesis mof; mof; greener synthesis; mof catalytic ... See more keywords