A fluorescent Eu(III) MOF for highly selective and sensitive sensing of picric acid
Sign Up to like & getrecommendations! Published in 2018 at "Science China Chemistry"
DOI: 10.1007/s11426-018-9367-y
Abstract: A metal-organic framework [Eu3L3(CH3COO)2(H2O)2(μ3-OH)]•3DMF, (EuL, H2L=9H-carbazole-2,7-dicarboxylic acid, DMF=N,N-dimethylformamide) has been synthesized under solvothermal conditions and structurally characterized. In EuL, Eu6O8 clusters are four-bridged by carboxylates to form parallel-aligned Eu–O–C chains, which are further linked by… read more here.
Keywords: highly selective; mof highly; picric acid; selective sensitive ... See more keywords
Pd/Cu-MOF as a highly efficient catalyst for synthesis of cyclopentanone compounds from biomass-derived furanic aldehydes
Sign Up to like & getrecommendations! Published in 2019 at "Catalysis Communications"
DOI: 10.1016/j.catcom.2019.04.008
Abstract: Abstract Herein, a series of Pd nanoparticles supported on Cu-MOFs (Cu3(BTC)2, FeCu-DMC) with pure Lewis acidity are synthesized for hydrogenative ring-rearrangement reaction of furanic aldehydes (furfural, 5-hydroxymethyl furfural) to cyclopentanone compounds (cyclopentanone, 3-hydroxymethyl cyclopentanone). For… read more here.
Keywords: furanic aldehydes; fecu dmc; cyclopentanone compounds; mof highly ... See more keywords
3D-monoclinic M–BTC MOF (M = Mn, Co, Ni) as highly efficient catalysts for chemical fixation of CO2 into cyclic carbonates
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Industrial and Engineering Chemistry"
DOI: 10.1016/j.jiec.2017.09.040
Abstract: Abstract [(CH3)2NH2][M3(BTC)(HCOO)4(H2O)].H2O (M–BTC, M = Mn, Ni, Co) were prepared under hydrothermal conditions and used as highly efficient catalysts for cycloaddition of CO2 with epichlorohydrin (ECH). The microstructure and physicochemical properties of the compounds were determined by… read more here.
Keywords: monoclinic btc; mof highly; btc; btc mof ... See more keywords
Porous MOF with Highly Efficient Selectivity and Chemical Conversion for CO2.
Sign Up to like & getrecommendations! Published in 2017 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.7b03835
Abstract: A new Co(II)-based MOF, {[Co2(tzpa)(OH)(H2O)2]·DMF}n (1) (H3tzpa = 5-(4-(tetrazol-5-yl)phenyl)isophthalic acid), was constructed by employing a tetrazolyl-carboxyl ligand H3tzpa. 1 possesses 1D tubular channels that are decorated by μ3-OH groups, uncoordinated carboxylate O atoms, and open… read more here.
Keywords: mof highly; co2; efficient selectivity; porous mof ... See more keywords
Mo-based 2D MOF as a highly efficient electrocatalyst for reduction of N2 to NH3: a density functional theory study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta02926e
Abstract: A Mo-based MOF is an efficient electrocatalyst for the N2 reduction reaction with a low overpotential of 0.18 V. read more here.
Keywords: mof highly; electrocatalyst reduction; based mof; efficient electrocatalyst ... See more keywords
Application of an Mn-MOF as a highly efficient catalyst for sunlight-driven hydrogen generation
Sign Up to like & getrecommendations! Published in 2018 at "Phase Transitions"
DOI: 10.1080/01411594.2018.1517211
Abstract: ABSTRACT Microscale crystals of a 2D layered Mn-MOF [Mn2(TylP)4]n (TylP=5-(1,2,4-triazol-1-yl)isophthalic) with a thiolate-bridged binuclear Mn(II) node similar to the active site of the [MnAu]-hydrogenase were prepared. This material shows high catalytic activity for visible-light-driven hydrogen… read more here.
Keywords: application mof; mof highly; driven hydrogen; hydrogen generation ... See more keywords