Step-Economical Photoassisted Diversity-Oriented Synthesis: Sustaining Cascade Photoreactions in Oxalyl Anilides to Access Complex Polyheterocyclic Molecular Architectures.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b07598
Abstract: Atom- and step-economy in photoassisted diversity-oriented synthesis (DOS) is achieved with a versatile oxalyl linker offering rapid access to complex alkaloid mimics in very few experimentally simple steps: (i) it allows for fast tethering of… read more here.
Keywords: photoassisted diversity; diversity oriented; molecular architectures; access complex ... See more keywords
Heterometallic Molecular Architectures Based on Fluorinated β-Diketone Ligands
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DOI: 10.3390/molecules27227894
Abstract: This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated β-diketonates. Heterometallic systems are of high interest in terms of their potential use in… read more here.
Keywords: molecular architectures; based fluorinated; fluorinated diketone; heterometallic molecular ... See more keywords
Microfluidic light-driven synthesis of tetracyclic molecular architectures
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DOI: 10.3762/bjoc.14.219
Abstract: Herein we report an effective synthetic method for the direct assembly of highly functionalized tetracyclic pharmacophoric cores. Coumarins and chromones undergo diastereoselective [4 + 2] cycloaddition reactions with light-generated photoenol intermediates. The reactions occur by… read more here.
Keywords: tetracyclic molecular; synthesis tetracyclic; molecular architectures; microfluidic light ... See more keywords
1,4-Dithianes: attractive C2-building blocks for the synthesis of complex molecular architectures
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DOI: 10.3762/bjoc.19.12
Abstract: This review covers the synthetic applications of 1,4-dithianes, as well as derivatives thereof at various oxidation states. The selected examples show how the specific heterocyclic reactivity can be harnessed for the controlled synthesis of carbon–carbon… read more here.
Keywords: molecular architectures; complex molecular; synthesis; dithianes attractive ... See more keywords