Step-Economical Photoassisted Diversity-Oriented Synthesis: Sustaining Cascade Photoreactions in Oxalyl Anilides to Access Complex Polyheterocyclic Molecular Architectures.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b07598
Abstract: Atom- and step-economy in photoassisted diversity-oriented synthesis (DOS) is achieved with a versatile oxalyl linker offering rapid access to complex alkaloid mimics in very few experimentally simple steps: (i) it allows for fast tethering of… read more here.
Keywords: photoassisted diversity; diversity oriented; molecular architectures; access complex ... See more keywords
Molecular architectures of iron complexes for oxygen reduction catalysis—Activity enhancement by hydroxide ions coupling
Sign Up to like & getrecommendations! Published in 2024 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2316553121
Abstract: Significance Iron phthalocyanine (FePc) has been utilized for catalyzing oxygen reduction reaction (ORR) as inspired by natural enzymes. The assembled FePc with relatively ordered nanotube morphology shows superior electrocatalytic ORR performance compared to FePc in… read more here.
Keywords: reduction; iron complexes; oxygen reduction; molecular architectures ... See more keywords
Heterometallic Molecular Architectures Based on Fluorinated β-Diketone Ligands
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DOI: 10.3390/molecules27227894
Abstract: This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated β-diketonates. Heterometallic systems are of high interest in terms of their potential use in… read more here.
Keywords: molecular architectures; based fluorinated; fluorinated diketone; heterometallic molecular ... See more keywords
Microfluidic light-driven synthesis of tetracyclic molecular architectures
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DOI: 10.3762/bjoc.14.219
Abstract: Herein we report an effective synthetic method for the direct assembly of highly functionalized tetracyclic pharmacophoric cores. Coumarins and chromones undergo diastereoselective [4 + 2] cycloaddition reactions with light-generated photoenol intermediates. The reactions occur by… read more here.
Keywords: tetracyclic molecular; synthesis tetracyclic; molecular architectures; microfluidic light ... See more keywords
1,4-Dithianes: attractive C2-building blocks for the synthesis of complex molecular architectures
Sign Up to like & getrecommendations! Published in 2023 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.19.12
Abstract: This review covers the synthetic applications of 1,4-dithianes, as well as derivatives thereof at various oxidation states. The selected examples show how the specific heterocyclic reactivity can be harnessed for the controlled synthesis of carbon–carbon… read more here.
Keywords: molecular architectures; complex molecular; synthesis; dithianes attractive ... See more keywords