Reversible Multielectron Release from Redox-Active Three-Dimensional Molecular Barrels with Ruthenium-Alkenyl Moieties.
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DOI: 10.1021/acs.inorgchem.2c01608
Abstract: Three-dimensional molecular barrels Ru6-4 and Ru6-5 were synthesized in high yields from dinuclear ruthenium-vinyl clamps and tritopic triphenylamine-derived carboxylate linkers and characterized by multinuclear NMR spectroscopy including 1H-1H COSY and 1H DOSY measurements, high-resolution electrospray… read more here.
Keywords: reversible multielectron; three dimensional; molecular barrels; multielectron release ... See more keywords