Shape-Persistent Oxa- and Aza-calix[4]arene Hybrid Molecular Cage and Naked Eye Sensing of Fluoride.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c02255
Abstract: An oxa- and aza-calix[4]arene hybrid molecular cage with a large, shape-persistent cavity wrapped by aromatic rings was designed and synthesized via multifold efficient SNAr reactions. X-ray single-crystal analysis revealed that two THF molecules were encapsulated… read more here.
Keywords: calix arene; molecular cage; aza calix; oxa aza ... See more keywords
A Cobalt Supramolecular Triple-Stranded Helicate-based Discrete Molecular Cage
Sign Up to like & getrecommendations! Published in 2017 at "Scientific Reports"
DOI: 10.1038/srep43448
Abstract: We report a strategy to achieve a discrete cage molecule featuring a high level of structural hierarchy through a multiple-assembly process. A cobalt (Co) supramolecular triple-stranded helicate (Co-TSH)-based discrete molecular cage (1) is successfully synthesized… read more here.
Keywords: molecular cage; supramolecular triple; cobalt supramolecular; cage ... See more keywords
Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc05613k
Abstract: A small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride… read more here.
Keywords: high affinity; molecular cage; cage high; cage ... See more keywords
An octahedral polyoxomolybdate-organic molecular cage.
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DOI: 10.1039/d0cc07120j
Abstract: An unprecedented Mo-organic molecular cage built on interesting {MoVI2O5} secondary building blocks and BTC ligands, which has been successfully synthesized and systematically characterized, presents the first example of an isopolyoxomolybdates(vi)-organic molecular cage. An investigation into… read more here.
Keywords: polyoxomolybdate organic; organic molecular; octahedral polyoxomolybdate; molecular cage ... See more keywords
Highly covalent molecular cage based porous organic polymer: pore size control and pore property enhancement
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DOI: 10.1039/d2ra02343a
Abstract: It remains a great challenge to effectively control the pore size in porous organic polymers (POPs) because of the disordered linking modes. Herein, we used organic molecular cages (OMCs), possessing the properties of fixed intrinsic… read more here.
Keywords: control pore; porous organic; cage based; molecular cage ... See more keywords