Articles with "molecular cages" as a keyword



Gold Catalysis in (Supra)Molecular Cages to Control Reactivity and Selectivity

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Published in 2019 at "Chemcatchem"

DOI: 10.1002/cctc.201801399

Abstract: Gold catalysis has experienced a tremendous development over the past decades, and is nowadays widely used in organic synthesis to perform chemical transformations of π‐bond‐containing molecules. Catalyst development has been based mostly on ligand development… read more here.

Keywords: molecular cages; gold catalysis; supra molecular; gold ... See more keywords

Biosynthesis of benzyl cinnamate using an efficient immobilized lipase entrapped in nano-molecular cages.

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Published in 2021 at "Food chemistry"

DOI: 10.1016/j.foodchem.2021.130428

Abstract: To improve the performance of lipase in biosynthesis of benzyl cinnamate, a new immobilized lipase by entrapping enzyme into nano-molecular cages was designed. Consequently, the entrapped lipase showed a robust immobilization, which diminished the leakage… read more here.

Keywords: molecular cages; biosynthesis benzyl; lipase; nano molecular ... See more keywords

Cooperative Anion-π Catalysis with Chiral Molecular Cages toward Enantioselective Desymmetrization of Anhydrides.

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Published in 2025 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c15978

Abstract: Exploiting novel noncovalent interactions for catalysis design represents a fascinating direction. For the flexible and relatively weak anion-π interactions, manipulation of two or more π-acidic surfaces for cooperative activation is highly desirable. Here, we demonstrate… read more here.

Keywords: desymmetrization; anion catalysis; anion; chiral molecular ... See more keywords

Comparing organic and metallo-organic hydrazone molecular cages as potential carriers for doxorubicin delivery

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Published in 2024 at "Chemical Science"

DOI: 10.1039/d4sc02294g

Abstract: Molecular cages are three-dimensional supramolecular structures that completely wrap guest molecules by encapsulation. We describe a rare comparative study between a metallo-organic cage and a fully organic analogous system, obtained by hydrazone bond formation self-assembly.… read more here.

Keywords: metallo organic; organic cage; delivery; cage ... See more keywords
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Azacryptands as molecular cages for anions and metal ions

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Published in 2018 at "Supramolecular Chemistry"

DOI: 10.1080/10610278.2017.1339885

Abstract: Abstract This is a short overview on azacryptands, as molecular receptors for cations and anions. A particular attention was devoted to the results obtained by women researchers working in the field. The terms ‘cryptand’ and… read more here.

Keywords: molecular cages; cages anions; metal ions; chemistry ... See more keywords

Improving the Encapsulation Efficiency of Lipase in Molecular Cages and Its Application.

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Published in 2023 at "Bioconjugate chemistry"

DOI: 10.2139/ssrn.4290596

Abstract: Here, lipase encapsulation is constructed by locking enzyme molecules in nanomolecular cages on the surface of SH-PEI@PVAC magnetic microspheres. To improve the encapsulation efficiency in enzyme loading, the thiol group is efficiently modified on the… read more here.

Keywords: molecular cages; encapsulation; encapsulated lipase; encapsulation efficiency ... See more keywords