Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2016.09.005
Abstract: Reduction of CO2 is a fruitful approach for storage of renewable electric energy as well as for the production of value added chemicals. Using variously substituted iron tetraphenylporphyrins and iron and cobalt macrocyclic pentadendate N5… read more here.
Keywords: catalysis electrochemical; reduction co2; catalysis; co2 ... See more keywords
Regulating the Spin State of FeIII Enhances the Magnetic Effect of the Molecular Catalysis Mechanism.
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DOI: 10.1021/jacs.2c01153
Abstract: Aqueous-phase oxygen evolution reaction (OER) is the bottleneck of water splitting. The formation of the O-O bond involves the generation of paramagnetic oxygen molecules from the diamagnetic hydroxides. The spin configurations might play an important… read more here.
Keywords: effect; feiii; molecular catalysis; mechanism ... See more keywords
The Role of Redox Potential and Molecular Structure of Co(II)-Polypyridine Complexes on the Molecular Catalysis of CO2 Reduction
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DOI: 10.3390/catal11080948
Abstract: In this work, we report the electrochemical response of a family of Co(II) complexes, [CoII(L)3]2+ and [CoII(L’)2]2+ (L = 2,2’-bipyridine, 1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, 5,6-dimethyl-1,10-phenanthroline, and 4,7-diphenyl-1,10-phenanthroline; L’ = terpyridine and 4-chloro-terpyridine), in the presence and absence… read more here.
Keywords: co2; co2 reduction; redox potential; molecular catalysis ... See more keywords